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Citation: LV Yan-Yang, LIU Xiao-Yu, CAO Jun. Synthesis and Characterization of Tetra(p-methoxy-phenyl) Porphyrin and Its Samarium(Ⅲ) Complexes[J]. Chinese Journal of Applied Chemistry, ;2010, 27(6): 691-694. doi: 10.3724/SP.J.1095.2010.90472 shu

Synthesis and Characterization of Tetra(p-methoxy-phenyl) Porphyrin and Its Samarium(Ⅲ) Complexes

College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000

Received Date: 15 July 2009
Revised Date: 26 October 2009

A new tetra(p-methoxy-phenyl) porphyrin Sm(Ⅲ) complex was obtained by the reaction of samarium chloride and tetra(p-methoxy-phenyl) porphyrin in THF in a yield of 62.4%.Besides the coordination reaction conditions,ligands and their complexes fluorescence properties were studied.Their structures were identified by UV-Vis,IR,¹H NMR and elemental analysis,which show that Sm(Ⅲ) complex has been formed.The reaction conditions were simple and easy to operate.
- meso-tetra(p-methoxy-phenyl)porphyrin,
- samarium(Ⅲ),
- synthesis,
- fluorescence spectral
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