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Citation: GUO Zhen-Zhen, CHEN Zhen, ZHENG Xi, CHEN Ri-Yao, CHEN Xiao. Electrolysis-generation of Furfural Alcohol and Furoic Acid in Pair by Ni-P-mCMC/mCS Bipolar Membrane[J]. Chinese Journal of Applied Chemistry, ;2010, 27(5): 579-584. doi: 10.3724/SP.J.1095.2010.90460 shu

Electrolysis-generation of Furfural Alcohol and Furoic Acid in Pair by Ni-P-mCMC/mCS Bipolar Membrane

GUO Zhen-Zhen ^a, ,
CHEN Zhen ^a,b ,
ZHENG Xi ^a ,
CHEN Ri-Yao ^a ,
CHEN Xiao ^a

a. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007;
b. Chemistry Department of Ningde College, Ningde 352100

Received Date: 13 July 2009
Revised Date: 20 October 2009

Ni-P-mCMC/mCS bipolar membrane(BPM) was prepared from carboxymethyl cellulose(CMC) modified with phosphorylated agent as a cation exchange layer and chitosan(CS) modified with glutaraldehyde(GA) as an anion exchange layer.The electrolysis cell was constituted by Ni-P-mCMC/mCS BPM as a septum for electro-generating furfural alcohol(in the cathode room) and furoic acid(in the anode room).The experiment results show that H⁺ generated by the BPM moves into the cathode room from the interface layer of the Ni-P-mCMC/mCS BPM to promote the electro-reduction of furfural for generating furfuryl alcohol;OH^- moves into the anode room to combine with H⁺ produced by electro-oxygenation of furfural to generate furoic acid and improve the forward reaction speed.The electrolysis efficiency was up to 82.4% in the cathode room and 77.4% in the anode room at 30℃ when the current density was 2.5 × 10^-2 A/cm².
- bipolar membrane,
- furfural alcohol,
- electroless nickel plating,
- electro-synthesis,
- furoic acid
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