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Citation: HUANG Xue-Hong, KE Sheng-Bo, JI Min. Preparation of Cross-linking Styrene-butadiene-styrene Triblock Copolymer Hybrid Bipolar Membrane and Its Application in Electro-generation of Trans-2,3-oxiranedicarboxylic Acid[J]. Chinese Journal of Applied Chemistry, ;2010, 27(11): 1306-1312. doi: 10.3724/SP.J.1095.2010.00026 shu

Preparation of Cross-linking Styrene-butadiene-styrene Triblock Copolymer Hybrid Bipolar Membrane and Its Application in Electro-generation of Trans-2,3-oxiranedicarboxylic Acid

College of Chemistry and Materials Science, Key Laboratory of Polymer Science, Fujian Normal University, Fuzhou 350007

Received Date: 11 January 2010
Revised Date: 26 April 2010

The cross-linking SBS hybrid bipolar membrane(SBS BPM) was prepared by free radical reaction of SBS(styrene-butadiene-styrene triblock copolymer) with acrylic acid(AA),sulfonic styrene(StSO₃H) and γ-methacryloxypropyltrimethoxysilane(KH-570) as the anode membrane,and reaction of SBS with dimethyl amino ethyl methacrylate(DMAEMA) and KH-570 as the cathode membrane.Cross-linking reaction was carried out through sol-gel reaction of trimethoxysilane group.SBS BPM exhibited high temperature tolerance(thermal degradation temperature in N₂,T_d was up to 186.5℃).The ion exchange capacities(IECs) of the anode and cathode membranes were 1.51 and 2.71 mmol/g,respectively.SBS hybrid bipolar membranes were used as the separator in the electrolysis cell,then using tungstate/pertungstate as the media to indirect electrooxidate maleic acid to prepare trans-2,3-oxiranedicarboxylic acid in the cathode chamber.Graphite was used as the anode and cathode electrode.At 50℃ and when the current density was 2.0 × 10^-2 A/cm² for 4 h,the yield and average current efficiency of trans-2,3-oxiranedicarboxylic acid were 53.0% and 40.8%,respectively.
- SBS hybrid bipolar membrane,
- indirect electrooxidate,
- tungstate/pertungstate,
- trans-oxiranedi-carboxylic acid
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