Citation: Qiang-qiang CHEN, Yu GUO, Hong-mei WU. Preparation of modified β zeolite with phosphorus for catalytic alkylation of C₉ aromatics with propylene[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(1): 98-108. doi: 10.19906/j.cnki.JFCT.2021074 shu

Preparation of modified β zeolite with phosphorus for catalytic alkylation of C₉ aromatics with propylene

School of Chemical and Environmental Engineering, Liaoning University of Technology, Jinzhou 121001, China

Corresponding author: Yu GUO, guoyu@lnut.edu.cn
Received Date: 8 May 2021
Revised Date: 16 July 2021

Figures(14)

To investigate the catalytic properties of β zeolite for catalytic alkylation of C₉ aromatics with propylene, β zeolites modified with phosphorus were prepared by using impregnation method. The modified β catalysts with different loading amount of phosphorus were characterized by XRD, SEM, EDX, MAS NMR, Py-IR, N₂ adsorption-desorption, and NH₃-TPD. The results showed that the morphology and crystal structure of the β zeolite catalysts did not change obviously after modification with phosphorus. However, the specific surface area and the surface Si/Al mass ratio of the β zeolite decreased with the increase of amount of phosphorus. It was proved that the interaction between the phosphorus and β zeolite could affect the acid strength distribution of β zeolite and the catalytic performance of alkylation of C₉ aromatics. In comparison with β zeolite, the β zeolite modified with 0.5% phosphorus (β-0.5P) had good catalytic performance in alkylation reaction of C₉ aromatics. The ratio of C₁₂₊ aromatics in the alkylation products was up to 17%, and the value of m_1,3,5-TMB/m_C9 was increased by 5.3%. The β-0.5P catalytic activity showed stable after reaction for 10 h. However, when the loading amount of phosphorus on β zeolite was too high, the alkylation activity of the catalyst decreased and the isomerization and disproportionation performance of the catalyst increased.
- β zeolite,
- modification,
- C₉ aromatics,
- propylene,
- alkylation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of modified β zeolite with phosphorus for catalytic alkylation of C9 aromatics with propylene

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通讯作者: 陈斌, bchen63@163.com

Preparation of modified β zeolite with phosphorus for catalytic alkylation of C₉ aromatics with propylene