Citation: Xin HUANG, Xi JIAO, Xiao-bo WANG, Ning ZHAO. Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(1): 44-53. doi: 10.19906/j.cnki.JFCT.2021073 shu

Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)

Xin HUANG ^1, ,
Xi JIAO ² ,
Xiao-bo WANG ^1,, ,
Ning ZHAO ³

1.
College of Safety and Emergency Management Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
Taiyuan University of Technology, Taiyuan 030024, China
3.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: Xiao-bo WANG, wxbtyut@163.com
Received Date: 11 June 2021
Revised Date: 16 July 2021

Figures(2)

Direct, nonoxidative conversion of methane towards olefins/aromatics is a hot topic in the background of “carbon peak, carbon neutrality”, owing to zero CO₂ emissions, high carbon atom utilization efficiency and hydrogen production. In the present paper, the advances of methane dehydroaromatization (MDA) and direct nonoxidative conversion of methane to olefins, aromatics, and hydrogen (MTOAH) are reviewed, based on our research works and the publications from 2018 to 2021. The determination of active sites, reaction intermediates, reaction mechanism, catalyst modification and improvement were considered. Finally, the future prospect was given for the direct nonoxidative conversion of methane to olefins/aromatics.
- methane,
- nonoxidative conversion,
- reaction mechanism,
- aromatics,
- single-atom catalysis
1. [1]
  ZHOU Shu-hui, WANG Jun, LIANG Yan. Development of China’s natural gas industry during the 14^th Five-Year Plan in the background of carbon neutrality[J]. Nat Gas Ind,2021,41(2):171−182. doi: 10.3787/j.issn.1000-0976.2021.02.02(
2. [2]
  BAO Xin-he. Nano confinement and catalytic conversion of energy molecules[J]. Chin Sci Bull,2018,63(14):1265−1274. doi: 10.1360/N972018-00441
3. [3]
  HUANG Xin, JIAO Xi, LIN Ming-gui, JIA Li-tao, HOU Bo, LI De-bao. Research progress in the direct nonoxidative dehydroaromatization of methane to aromatics[J]. J Fuel Chem Technol,2018,46(9):1087−1100. doi: 10.3969/j.issn.0253-2409.2018.09.008
4. [4]
  UPHAM C, AGARWAL V, KHECHFE A, SNODGRASS Z R, GORDON M J, METIU H, MCFARLAND E W. Catalytic molten metals for the direct conversion of methane to hydrogen and separable carbon[J]. Science,2017,358:917−921. doi: 10.1126/science.aao5023
5. [5]
  DÍZA-URRUTIA C, OTT T. Activation of methane to CH₃⁺: A selective industrial route to methanesulfonic acid[J]. Science,2019,363:1326−1329. doi: 10.1126/science.aav0177
6. [6]
  SONG Y, OZDEMIR E, RAMESH S, ADISHEV A, SUBRAMANIAN S, HARALE A, ALBUALI M, FADHEL B A, JAMAL A, MOON D, CHOI S, YAVUZ C. Dry reforming of methane by stable Ni-Mo nanocatalysts on single-crystalline MgO[J]. Science,2020,367:777−781. doi: 10.1126/science.aav2412
7. [7]
  JIN Z, WANG L, ZUIDEMA E, MONDAL K, ZHANG M, ZHANG J, WANG C, MENG X, YANG H, MESTERS C, XIAO F. Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol[J]. Science,2020,367:193−197. doi: 10.1126/science.aaw1108
8. [8]
  WANG L, TAO L, XIE M, XU G, HUANG J, XU Y. Dehydrogenation and aromatization of methane under non-oxidizing conditions[J]. Catal Lett,1993,21:35−41. doi: 10.1007/BF00767368
9. [9]
  GUO X, FANG G, LI G, MA H, FAN H, YU L, MA C, WU X, DENG D, WEI M, TAN D, SI R, ZHANG S, LI J, SUN L, TANG Z, PAN X, BAO X. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen[J]. Science,2014,344:616−619. doi: 10.1126/science.1253150
10. [10]
  VOLLMER I, YARULINA I, KAPTEIJN F, GASCON J. Progress in developing a structure-activity relationship for the direct aromatization of methane[J]. ChemCatChem,2019,11:39−52. doi: 10.1002/cctc.201800880
11. [11]
  SCHWACH P, PAN X, BAO X. Direct conversion of methane to value-added chemicals over heterogeneous catalysts: challenges and prospects[J]. Chem Rev,2017,117:8497−8520. doi: 10.1021/acs.chemrev.6b00715
12. [12]
  KOSINOV N, HENSEN E. Reactivity, selectivity, and stability of zeolite-based catalysts for methane dehydroaromatization[J]. Adv Mater,2020,2002565.
13. [13]
  XU Y, BAO X, LIN L. Direct conversion of methane under nonoxidative conditions[J]. J Catal,2003,216:386−395. doi: 10.1016/S0021-9517(02)00124-0
14. [14]
  MA S, GUO X, ZHAO L, SCOTT S, BAO X. Recent progress in methane dehydroaromatization: from laboratory curiosities to promising technology[J]. J Energy Chem,2013,22:1−20. doi: 10.1016/S2095-4956(13)60001-7
15. [15]
  ISMAGILOV Z, MATUS E, TSIKOZA L. Direct conversion of methane on Mo/ZSM-5 catalysts to produce benzene and hydrogen: achievements and perspectives[J]. Energy Environ Sci,2008,1:526−541. doi: 10.1039/b810981h
16. [16]
  SPIVEY J, HUTCHINGS G. Catalytic aromatization of methane[J]. Chem Soc Rev,2014,43:792−803. doi: 10.1039/C3CS60259A
17. [17]
  KIANI D, SOURAV S, TANG Y, BALTRUSAITIS J, WACHS I. Methane activation by ZSM-5-supported transition metal centers[J]. Chem Soc Rev,2021,50:1251−1268. doi: 10.1039/D0CS01016B
18. [18]
  MENON U, RAHMAN M, KHATIB S. A critical literature review of the advances in methane dehydroaromatization over multifunctional metal-promoted zeolite catalysts[J]. Appl Catal A: Gen,2020,608:117870. doi: 10.1016/j.apcata.2020.117870
19. [19]
  XU Y, YUAN X, CHEM M, DONG A, LIU B, JIANG F, YANG S, LIU X. Identification of atomically dispersed Fe-oxo species as new active sites in HZSM-5 for efficient nonoxidative methane dehydroaromatization[J]. J Catal,2021,396:224−241. doi: 10.1016/j.jcat.2021.02.028
20. [20]
  XU Y, CHEM M, WANG T, LIU B, JIANG F, LIU X. Probing cobalt localization of HZSM-5 for efficient methane dehydroaromatization catalysts[J]. J Catal,2020,387:102−118. doi: 10.1016/j.jcat.2020.04.021
21. [21]
  XU Y, CHEM M, LIU B, JIANG F, LIU X. CH₄ conversion over Ni/HZSM-5 catalyst in the absence of oxygen: decomposition or dehydroaromatization[J]. Chem Commun,2020,56:4396−4399. doi: 10.1039/D0CC01345E
22. [22]
  THAKUR R, HOFFMAN M, VAHIDMOHAMMAD A, SMITH J, CHI M, TATARCHUK B, BEIDAGHI M, CARRERO C. Multilayered two-dimensional V₂CT_x MXene for methane dehydroaromatization[J]. ChemCatChem,2020,12:3639−3643. doi: 10.1002/cctc.201902366
23. [23]
  DUTTA K, LI L, GUPTA P, GURIERREZ D, KOPYSCINSKI J. Direct non-oxidative methane aromatization over gallium nitride catalyst in a continuous flow reactor[J]. Catal Commun,2018,108:16−19.
24. [24]
  KANITKAR S, ABEDIN M, BHATTAR S, SPIVEY J. Methane dehydroaromatization over molybdenum supported on sulfated zirconia catalysts[J]. Appl Catal A: Gen,2019,575:25−37. doi: 10.1016/j.apcata.2019.01.013
25. [25]
  LEZCAO-GONZÁLEZ I, OORD R, ROVEZZI M, GLATZEL P, BOTCHWAY S, WECKHUYSEN B, BEALE A. Molybdenum speciation and its impact on catalytic activity during methane dehydroaromatization in zeolite ZSM-5 as revealed by operando X-ray methods[J]. Angew Chem Int Ed,2016,55:5215−5219. doi: 10.1002/anie.201601357
26. [26]
  AGOTE-ARÁN M, KRONER A, ISLAM H, SŁAWIŃSKI W, WRAGG D, LEZCAO-GONZÁLEZ I, BEALE A. Determination of molybdenum species evolution during non-oxidative dehydroaromatization of methane and its implications for catalytic performance[J]. ChemCatChem,2019,11:473−480. doi: 10.1002/cctc.201801299
27. [27]
  AGOTE-ARÁN M, FLETCHER R, BRICENO M, KRONER A, SAZANOVICH I, SLATER B, RIVAS M, SMITH A, COLLIER P, LEZCAO-GONZÁLEZ I, BEALE A. Implications of the molybdenum coordination environment in MFI zeolites on methane dehydroaromatization performance[J]. ChemCatChem,2020,12:294−304. doi: 10.1002/cctc.201901166
28. [28]
  AGOTE-ARÁN M, KRONER A, WRAGG D, SŁAWIŃSKI W, BRICENO M, ISLAM H, SAZANOVICH I, RIVAS M, SMITH A, COLLIER P, LEZCAO-GONZÁLEZ I, BEALE A. Understanding the deactivation phenomena of small-pore Mo/H-SSZ-13 during methane dehydroaromatization[J]. Molecules,2020,25:5048. doi: 10.3390/molecules25215048
29. [29]
  KOSINOV N, WIJPKEMA A, USLAMIN E, ROHLING R, COUMANS F, MEZARI B, PARASTAEV A, PORYVAEV A, FEDIN M, PIDKO E, HENSEN E. Confined carbon mediating dehydroaromatization of methane over Mo/ZSM-5[J]. Angew Chem Int Ed,2018,57:1016−1020. doi: 10.1002/anie.201711098
30. [30]
  VOLLMER I, KOSINOV N, SZÉCSÉNYI Á, LI G, YARULINA I, ABOU-HAMAD E, GURINOV A, OULD-CHIKH S, AGUILAR-TAPIA A, HAZEMANN J, PIDKO E, HENSEN E, KAPTEIJN F, GASCON J. A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation[J]. J Catal,2019,370:321−331. doi: 10.1016/j.jcat.2019.01.013
31. [31]
  LIU L, WANG N, ZHU C, LIU X, ZHU Y, GUO P, ALFILFIL L, DONG X, ZHANG D, HAN Y. Direct imaging of atomically dispersed molybdenum that enables location of aluminum in the framework of zeolite ZSM-5[J]. Angew Chem Int Ed,2020,132:829−835. doi: 10.1002/ange.201909834
32. [32]
  KONNOV S, DUBRAY F, CLATWORTHY E, KOUVATAS C, GILSON J, DATH J, MINOUX D, AQUINO C, VALTCHEV V, MOLDOVAN S, KONETI S, NESTERENKO N, MINTOVA S. Novel strategy for the synthesis of ultra-stable single-site Mo-ZSM-5 zeolite nanocrystals[J]. Angew Chem Int Ed,2020,59:19553−19560. doi: 10.1002/anie.202006524
33. [33]
  WANG D, LUNSFORD J, ROSYNEK M. Catalytic conversion of methane to benzene over Mo/ZSM-5[J]. Top Catal,1996,3:289−297. doi: 10.1007/BF02113855
34. [34]
  VOLLMER I, ABOU-HAMAD E, GASCON J, KAPTEIJN F. Aromatization of ethylene-main intermediate for MDA[J]. ChemCatChem,2020,12:544−549. doi: 10.1002/cctc.201901655
35. [35]
  MÉRIAUDEAU P, TIEP L, HA V, NACCACHE C, SZABO G. Aromatization of methane over Mo/H-ZSM-5 catalyst: on the possible reaction intermediates[J]. J Mol Catal A: Chem,1999,144:469−471. doi: 10.1016/S1381-1169(99)00050-3
36. [36]
  MÉRIAUDEAU P, HA V, TIEP L. Methane aromatization over Mo/H-ZSM-5: on the reaction pathway[J]. Catal Lett,2000,64:49−51. doi: 10.1023/A:1019014431678
37. [37]
  HA V, TIEP L, MÉRIAUDEAU P, NACCACHE C. Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism[J]. J Mol Catal A: Chem,2002,181:283−290. doi: 10.1016/S1381-1169(01)00373-9
38. [38]
  RAZDAN N, KUMAR A, FOLEY B, BHAN A. Influence of ethylene and acetylene on the rate and reversibility of methane dehydroaromatization on Mo/H-ZSM-5 catalysts[J]. J Catal,2020,381:261−270. doi: 10.1016/j.jcat.2019.11.004
39. [39]
  CHEN L, LIN L, XU Z, LI X, ZHANG T. Dehydro-oligomerization of methane to ethylene and aromatics over molybdenum/HZSM-5 catalyst[J]. J Catal,1995,157:190−200. doi: 10.1006/jcat.1995.1279
40. [40]
  XU Y, LIU S, WANG L, XIE M, GUO X. Methane activation without using oxidants over Mo/HZSM-5 zeolite catalysts[J]. Catal Lett,1995,30:135−149. doi: 10.1007/BF00813680
41. [41]
  LIU S, WANG L, OHNISHI R, ICHIKAWA M. Bifunctional catalysis of Mo/HZSM-5 in the dehydroaromatization of methane to benzene and naphthalene XAFS/TG/DTA/MASS/FTIR characterization and supporting effects[J]. J Catal,1999,181:175−188. doi: 10.1006/jcat.1998.2310
42. [42]
  SHU J, ADNOT A, GRANDJEAN B. Bifunctional behavior of Mo/HZSM-5 catalysts in methane aromatization[J]. Ind Eng Chem Res,1999,38:3860−3867. doi: 10.1021/ie990145i
43. [43]
  LIU S, WANG L, OHNISHI R, ICHIKAWA M. Bifunctional catalysis of Mo/HZSM-5 in the dehydroaromatization of methane with CO/CO₂ to benzene and naphthalene[J]. Kinet Catal,2000,41:132−144. doi: 10.1007/BF02756152
44. [44]
  MA D, SHU Y, CHENG M, XU Y, BAO X. On the induction period of methane aromatization over Mo-based catalysts[J]. J Catal,2000,194:105−114. doi: 10.1006/jcat.2000.2908
45. [45]
  DING W, LI S, MEITZNER G, IGLESIA E. Methane conversion to aromatics on Mo/HZSM-5: Structure of molybdenum species in working catalysts[J]. J Phys Chem B,2001,105:605−513.
46. [46]
  DING W, MEITZNER G, MARLER D, IGLESIA E. Synthesis, structural characterization, and catalytic properties of tungsten-exchanged H-ZSM5[J]. J Phys Chem B,2001,105:3928−3936. doi: 10.1021/jp003413v
47. [47]
  DING W, MEITZNER G, IGLESIA E. The effects of silanation of external acid sites on the structure and catalytic behavior of Mo/H-ZSM5[J]. J Catal,2002,206:14−22. doi: 10.1006/jcat.2001.3457
48. [48]
  KOSINOV N, COUMANS F, USLAMIN E, WIJPKEMA S, MEZARI B, HENSEN E. Methane dehydroaromatization by Mo/HZSM-5: Mono- or bifunctional catalysis[J]. ACS Catal,2017,7:520−529. doi: 10.1021/acscatal.6b02497
49. [49]
  KOSINOV N, USLAMIN E, COUMANS J, WIJPKEMA A, ROHLING R, HENSEN E. Structure and evolution of confined carbon species during methane dehydroaromatization over Mo/ZSM-5[J]. ACS Catal,2018,8:8459−8467. doi: 10.1021/acscatal.8b02491
50. [50]
  VOLLMER I, LINDEN B, OULD-CHIKH S, AGUILAR-TAPIA A, YARULINA I, ABOU-HAMAD E, SNEIDER Y, SUZREZ A, HAZEMANN J, KAPTEIJN F, GASCON J. On the dynamic nature of Mo sites for methane dehydroaromatization[J]. Chem Sci,2018,9:4801−4807. doi: 10.1039/C8SC01263F
51. [51]
  CAGLAYAN M, PAIONI A, ABOU-HAMAD E, SHTERK G, PUSTOVARENKO A, BALDUS M, CHOWDHURY A, GASCON J. Initial carbon-carbon bond formation during the early stages of methane dehydroaromatization[J]. Angew Chem Int Ed,2020,59:16741−16746. doi: 10.1002/anie.202007283
52. [52]
  GAO W, QI G, WANG Q, WANG W, LI S, HUNG I, GAO Z, XU J, DENG F. Dual active sites on molybdenum/ZSM-5 catalyst for methane dehydroaromatization: Insight from solid-state NMR spectroscopy[J]. Angew Chem Int Ed,2021,60:10709−10715. doi: 10.1002/anie.202017074
53. [53]
  WANG K, HUANG X, LI D. Hollow ZSM-5 zeolite grass ball catalyst in methane dehydroaromatization: one-step synthesis and the exceptional catalytic performance[J]. Appl Catal A: Gen,2018,556:10−19. doi: 10.1016/j.apcata.2018.02.030
54. [54]
  HUANG X, JIAO X, LIN M, WANG K, JIA L, HOU B, LI D. Coke distribution determines the lifespan of a hollow Mo/HZSM-5 capsule catalyst in CH₄ dehydroaromatization[J]. Catal Sci Technol,2018,8:5740−5749. doi: 10.1039/C8CY01391H
55. [55]
  JIAO X, HUANG X, WANG K. In situ UV-Raman spectroscopy of the coking-caused deactivation mechanism over an Mo/HMCM-22 catalyst in methane dehydroaromatization[J]. Catal Sci Technol,2019,9:6552−6555. doi: 10.1039/C9CY01932D
56. [56]
  VOLLMER I, LI G, YARULINA I, KOSINOV N, HENSEN E, HOUBEN K, MANCE D, BALDUS M, GASCON J, KAPTEIJN F. Relevance of the Mo-precursor state in H-ZSM-5 for methane dehydroaromatization[J]. Catal Sci Technol,2018,8:916−922. doi: 10.1039/C7CY01789H
57. [57]
  KOSINOV N, USLAMIN E, MENG L, PARASTAEV A, LIU Y, HENSEN E. Reversible nature of coke formation on Mo/ZSM-5 methane dehydroaromatization catalysts[J]. Angew Chem Int Ed,2019,131:7142−7146. doi: 10.1002/ange.201902730
58. [58]
  JULIAN I, ROEDERN M, HUESO J, IRUSTA S, BADEN A, MALLADA R, DAVIS Z, SANTAMARIA J. Supercritical solvothermal synthesis under reducing conditions to increase stability and durability of Mo/ZSM-5 catalysts in methane dehydroaromatization[J]. Appl Catal B: Environ,2020,263:118360. doi: 10.1016/j.apcatb.2019.118360
59. [59]
  BALYAN S, HAIDER M, KHAN T, PANT K. Boric acid treated HZSM-5 for improved catalyst activity in non-oxidative methane dehydroaromatization[J]. Catal Sci Technol,2020,10:3857−3867. doi: 10.1039/D0CY00286K
60. [60]
  GU Y, CHEN P, YAN H, WANG X, LYU Y, TIAN Y, LIU W, YAN Z, LIU X. Coking mechanism of Mo/ZSM-5 catalyst in methane dehydroaromatization[J]. Appl Catal A: Gen,2021,613:118019. doi: 10.1016/j.apcata.2021.118019
61. [61]
  ZHANG Y, JIANG H. A novel route to improve methane aromatization by using a simple composite catalyst[J]. Chem Commun,2018,54:10343−10346. doi: 10.1039/C8CC05059G
62. [62]
  KUMAR A, SONG K, LIU L, HAN Y, BHAN A. Absorptive hydrogen scavenging for enhanced aromatics yield during non-oxidative methane dehydroaromatization on Mo/H-ZSM-5 catalysts[J]. Angew Chem Int Ed,2018,57:15577−15582. doi: 10.1002/anie.201809433
63. [63]
  SIM J, LEE B, HAN G, KIM D, LEE K. Promotional effect of Au on Fe/HZSM-5 catalyst for methane dehydroaromatization[J]. Fuel,2020,274:117852. doi: 10.1016/j.fuel.2020.117852
64. [64]
  HAN S, LEE S, KIM H, KIM S, KIM Y. Nonoxidative direct conversion of methane on silica-based iron catalysts: Effect of catalytic surface[J]. ACS Catal,2019,9:7984−7997. doi: 10.1021/acscatal.9b01643
65. [65]
  SOT P, NEWTON M, BAABE D, MALTER M, BAVEL A, HORTON A, COPERET C, BOKHOVEN J. Non-oxidative methane coupling over silica versus silica-supported iron(II) single sites[J]. Chem A Euro J,2020,26:8012−8016. doi: 10.1002/chem.202001139
66. [66]
  EGGART D, ZIMINA A, CAVUSOGLU G, CASAPU M, DORONKIN D, LOMACHENKO K, GRUNWALDT J. Versatile and high temperature spectroscopic cell for operando fluorescence and transmission X-ray absorption spectroscopy studies of heterogeneous catalysts[J]. Rev Sci Instrum,2021,92:023106. doi: 10.1063/5.0038428
67. [67]
  XIE P, PU T, NIE A, HWANG S, PURDY S, YU W, SU D, MILLER J, WANG C. Nanoceria-supported single-atom platinum catalysts for direct methane conversion[J]. ACS Catal,2018,8:4044−4048. doi: 10.1021/acscatal.8b00004
68. [68]
  XIAO Y, VARMA A. Highly selective nonoxidative coupling of methane over Pt-Bi bimetallic catalysts[J] ACS Catal, 2018, 8: 2735−2740.
69. [69]
  DIPU A, OHBUCHI S, NISHIKAWA Y, IGUCHI S, OGIHARA H, YAMANAKA I. Direct nonoxidative conversion of methane to higher hydrocarbons over silica-supported nickel phosphide catalyst[J] ACS Catal, 2020, 10: 375−379.
70. [70]
  HAO J, SCHWACH P, LI L, GUO X, WENG J, ZHANG H, SHEN H, FANG G, HUANG X, PAN X, XIAO C, YANG X, BAO X. Direct experimental detection of hydrogen radicals in non-oxidative methane catalytic reaction[J]. J Energy Chem,2021,52:372−376. doi: 10.1016/j.jechem.2020.04.001
71. [71]
  LIU Y, LIU J, LI T, DUAN Z, ZHANG T, YAN M, LI W, XIAO H, WANG Y, CHANG C, LI J. Unravelling the enigma of nonoxidative conversion of methane on iron single-atom catalysts[J]. Angew Chem Int Ed,2020,59:18586−18590. doi: 10.1002/anie.202003908
72. [72]
  HAO J, SCHWACH P, FANG G, GUO X, ZHANG H, SHEN H, HUANG X, EGGART D, PAN X, BAO X. Enhanced methane conversion to olefins and aromatics by H-donor molecules under nonoxidative condition[J]. ACS Catal,2019,9:9045−9050. doi: 10.1021/acscatal.9b01771
73. [73]
  SAKBODIN M, WU Q, OH S, WACHSMAN E, LIU D. Hydeogen-permeable tubular membrane reactor: promoting conversion and product selectivity for non-oxidative activation of methane over an Fe©SiO₂ catalyst[J]. Angew Chem Int Ed,2016,55:16149−16152. doi: 10.1002/anie.201609991
74. [74]
  OH S, SCHULAMAN E, ZHANG J, FAN J, PAN Y, MENG J, LIU D. Direct non-oxidative methane conversion in a millisecond catalytic wall reactor[J]. Angew Chem Int Ed,2019,58:7083−7086. doi: 10.1002/anie.201903000
75. [75]
  KIM H, LEE S, NA G, HAN S, KIM S, SHIN J, CHANG H, KIM Y. Reaction condition optimization for non-oxidative conversion of methane using artificial intelligence[J]. React Chem Eng,2021,6:235−243. doi: 10.1039/D0RE00378F
76. [76]
  POSTMA R, LEFFERTS L. Influence of axial temperature profiles on Fe/SiO₂ catalyzed non-oxidative coupling of methane[J]. ChemCatChem,2021,13:1157−1160. doi: 10.1002/cctc.202001785
77. [77]
  ZHANG X, YOU R, WEI Z, JIANG X, YANG J, PAN Y, WU P, JIA Q, BAO Z, BAI L, JIN M, SUMPTER B, FUNG V, HUANG W, WU Z. Radical chemistry and reaction mechanisms of propane oxidative dehydrogenation over hexagonal boron nitride catalysts[J]. Angew Chem Int Ed,2020,59:8042−8046. doi: 10.1002/anie.202002440
78. [78]
  SUN Yang, DING Dou-dou, LIN Chang, LIU Xiang-lin, ZHANG Chao, TIAN Peng-fei, CAO Chen-xi, YANG Zi-xu, XU Jin, HAN Yi-fan. Advances in operando techniques for the heterogeneous catalytic reactions[J]. Chem Ind Eng Prog,2019,38(1):260−277.
1. [1]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
2. [2]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
3. [3]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
4. [4]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
5. [5]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
6. [6]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
7. [7]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
8. [8]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
9. [9]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172
10. [10]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
11. [11]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
12. [12]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
13. [13]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
14. [14]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
15. [15]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
18. [18]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1657)
HTML views(460)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142