Citation: Li-ye ZHAO, Heng LI, Liang WANG, Chun-hu LI. Effect of halogen atoms on photocatalytic activity of bismuth oxyhalide (BIOX, X = Cl, Br, I)[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(1): 122-128. doi: 10.19906/j.cnki.JFCT.2021067 shu

Effect of halogen atoms on photocatalytic activity of bismuth oxyhalide (BIOX, X = Cl, Br, I)

College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China

Corresponding author: Heng LI, liheng@ouc.edu.cn Liang WANG, wangliang_good@163.com
Received Date: 28 April 2021
Revised Date: 21 June 2021

Figures(9)

BiOCl, BiOBr and BiOI were prepared by hydrothermal and solvothermal methods. XRD, SEM, photocurrent density curve and UV-vis were used to characterize the crystal structure, surface morphology and photoelectric properties. The band structure and density of states of BiOX were calculated by DFT. With the atomic number of halogen increase, the dispersion of the Fermi level near the semiconductor conduction band decreases, and the band gap becomes smaller. The photocatalytic activity of BiOCl, BiOBr and BiOI was evaluated by photocatalytic degradation of Rhodamine B (RhB), and the degradation rate of RhB in 60 min for BiOI could reach 100%. Meanwhile, the main active groups in the process of photocatalytic degradation of RhB were explored by radical trapping experiment.
- BiOX,
- halogen atom,
- photocatalysis,
- photocatalytic performance
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