Citation: Li-ye ZHAO, Heng LI, Liang WANG, Chun-hu LI. Effect of halogen atoms on photocatalytic activity of bismuth oxyhalide (BIOX, X = Cl, Br, I)[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(1): 122-128. doi: 10.19906/j.cnki.JFCT.2021067 shu

Effect of halogen atoms on photocatalytic activity of bismuth oxyhalide (BIOX, X = Cl, Br, I)

College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China

Corresponding author: Heng LI, liheng@ouc.edu.cn Liang WANG, wangliang_good@163.com
Received Date: 28 April 2021
Revised Date: 21 June 2021

Figures(9)

BiOCl, BiOBr and BiOI were prepared by hydrothermal and solvothermal methods. XRD, SEM, photocurrent density curve and UV-vis were used to characterize the crystal structure, surface morphology and photoelectric properties. The band structure and density of states of BiOX were calculated by DFT. With the atomic number of halogen increase, the dispersion of the Fermi level near the semiconductor conduction band decreases, and the band gap becomes smaller. The photocatalytic activity of BiOCl, BiOBr and BiOI was evaluated by photocatalytic degradation of Rhodamine B (RhB), and the degradation rate of RhB in 60 min for BiOI could reach 100%. Meanwhile, the main active groups in the process of photocatalytic degradation of RhB were explored by radical trapping experiment.
- BiOX,
- halogen atom,
- photocatalysis,
- photocatalytic performance
1. [1]
  FENG X F, YU Z X, SUN Y X, LONG RX, SHAN M Y, LI X H, LIU Y C, LIU J H. Review MXenes as a new type of nanomaterial for environmental applications in the photocatalytic degradation of water pollutants[J]. Ceram Int,2020,47(6):7321−7343.
2. [2]
  ZHU Ze-zhou. Engineering the interface sites for photocatalytic/electrocatalytic CO₂ reduction[D]. Hefei: University of Science and Technology of China, 2020.
3. [3]
  AHMAD K, GHATAK H R, AHUJA S M. A review on photocatalytic remediation of environmental pollutants and H₂ production through water splitting: A sustainable approach[J]. Environ Technol Innovation,2020,19:100893.
4. [4]
  FUJISHIMA, A., HONDA, K. Photolysis of water at a semiconductor electrode[J]. Nature,1972,238:37−38. doi: 10.1038/238037a0
5. [5]
  YANG Fan. Precise structure control of TiO₂ composite materials and its photocatalytic performance[D]. Hefei: University of Science and Technology of China, 2020.
6. [6]
  HUANG X J, GUO Q B, YAN B C, LIU H, CHEN K, WEI S S, WU Y H, WANG L. Study on photocatalytic degradation of phenol by BiOI/Bi₂WO₆ layered heterojunction synthesized by hydrothermal method[J]. J Mol Liq,2021,322:114965. doi: 10.1016/j.molliq.2020.114965
7. [7]
  LIU H J, WANG B J, CHEN M, ZHANG H, PENG J B, DING L, WANG W F. Simple synthesis of BiOAc/BiOBr heterojunction composites for the efficient photocatalytic removal of organic pollutants[J]. Sep Purif Technol,2021,261:118286. doi: 10.1016/j.seppur.2020.118286
8. [8]
  MOKHTARI F, TAHMASEBI N. Hydrothermal synthesis of W-doped BiOCl nanoplates for photocatalytic degradation of rhodamine B under visible light[J]. J Phys Chem Solids,2021,149:109804. doi: 10.1016/j.jpcs.2020.109804
9. [9]
  WANG Y, SUNARSO J, ZHAO B, GE C H, CHNE G H. One-dimensional BiOBr nanosheets/TiO₂ nanofibers composite: Controllable synthesis and enhanced visible photocatalytic activity[J]. Ceram Int,2017,43(17):15769−15776. doi: 10.1016/j.ceramint.2017.08.140
10. [10]
  YE L Q, JIN X L, LENG Y M, SU Y R, XIE H Q, LIU C. Synthesis of black ultrathin BiOCl nanosheets for efficient photocatalytic H₂ production under visible light irradiation[J]. J Power Sources,2015,293:409−415. doi: 10.1016/j.jpowsour.2015.05.101
11. [11]
  CUI Y H, YANG L L, ZHENG J, WANG Z K, LI B R, YAN Y, MENG M J. Synergistic interaction of Z-scheme 2D/3D g-C₃N₄/BiOI heterojunction and porous PVDF membrane for greatly improving the photodegradation efficiency of tetracycline[J]. J Colloid Interf Sci,2021,586:335−348. doi: 10.1016/j.jcis.2020.10.097
12. [12]
  BARHOUMI M, SAID M. Correction of band-gap energy and dielectric function of BiOX bulk with GW and BSE[J]. Optik,2020,216:164631. doi: 10.1016/j.ijleo.2020.164631
13. [13]
  YE L Q, DENG K J, XU F, TIAN LH, PENG T Y, ZAN L. Increasing visible-light absorption for photocatalysis with black BiOCl[J]. Chem Chem Phys, 2012, 14: 82–85.
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沈阳化工大学材料科学与工程学院沈阳 110142