Citation: Yun-peng ZHAO, Xing-gang SI, Wei ZHAO, Jing-pei CAO, Xian-yong WEI. Catalytic hydrodeoxygenation of lignite-derived model compounds to monomeric hydrocarbons over Co/Al₂O₃[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 160-167. doi: 10.19906/j.cnki.JFCT.2021032 shu

Catalytic hydrodeoxygenation of lignite-derived model compounds to monomeric hydrocarbons over Co/Al₂O₃

Yun-peng ZHAO ^{1, 2,,} ,
Xing-gang SI ¹ ,
Wei ZHAO ¹ ,
Jing-pei CAO ^1,, ,
Xian-yong WEI ^{1, 2}

1.
Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China
2.
Key Laboratory of Coal Clean Conversion & Chemical Engineering Process of Xinjiang Uygur Autonomous Region, College of Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: Yun-peng ZHAO, zhaoyp@cumt.edu.cn Jing-pei CAO, caojingpei@cumt.edu.cn
Received Date: 25 September 2020
Revised Date: 22 October 2020

Figures(9)

A Co/Al₂O₃ catalyst was synthesized by facile calcination and hydrogen reduction of a cobalt-aluminum hydrotalcite CoAl-LDH, and the X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photon spectroscopy (XPS) were used to characterize the physical and chemical properties of the precursor and catalysts. Using 2-naphthyl ether as the lignite derived model compound, the catalytic performance of Co/Al₂O₃ on the hydrodeoxygenation of 2-naphthyl ether to monomeric hydrocarbons was investigated. The results show that Co/Al₂O₃-700 has the highest hydrodeoxygenation activity. Under the conditions of 250 ℃, 2 MPa of initial H₂ pressure and_{90 min of holding time, the 2-naphthyl ether is completely converted to monomeric hydrocarbons (decalin and tetralin), in which the 2-naphthyl ether is first converted to 6,6'-oxybis (1,2,3,4-tetrahydronaphthalene) by hydrogenation and then the tetralin and 5,6,7,8-tetrahydronaphthalene-2-naphthol are formed by the cleavage of C−O bond. In addition, Co/Al₂O₃-700 also shows high activity for the hydrodeoxygenation of lignite-derived benzyl ether and phenyl ether model compounds.}
- Co/Al₂O₃ catalyst,
- hydrodeoxygenation,
- lignite-derived model compounds,
- monomeric hydrocarbons
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic hydrodeoxygenation of lignite-derived model compounds to monomeric hydrocarbons over Co/Al2O3

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通讯作者: 陈斌, bchen63@163.com

Catalytic hydrodeoxygenation of lignite-derived model compounds to monomeric hydrocarbons over Co/Al₂O₃