Citation: Chang-ming LIANG, An-dong ZAHNG, Zhi-he LI, Yu-feng LI, Shao-qing WANG, Wei-ming YI. Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 168-177. doi: 10.19906/j.cnki.JFCT.2021016 shu

Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst

Chang-ming LIANG ^{1, 2,} ,
An-dong ZAHNG ^{1, 2} ,
Zhi-he LI ^{1, 2,,} ,
Yu-feng LI ^{1, 2} ,
Shao-qing WANG ^{1, 2} ,
Wei-ming YI ^{1, 2}

1.
College of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China

Corresponding author: Zhi-he LI, lizhihe@sdut.edu.cn
Received Date: 15 October 2020
Revised Date: 20 November 2020

Figures(13)

In order to realize high value utilization of wood vinegar, a series of Ni based catalysts with different Co contents prepared by impregnation method were tested in a fixed bed reactor. The effects of liquid space-time velocity, reaction temperature and Ni/Co ratio on hydrogen production, carbon conversion, H₂ selectivity and carbon deposition were investigated. The catalysts were characterized by XRF, H₂-TPR, SEM and elemental analysis. The results show that the gas production increases with the increase of space-time velocity of liquid, but the catalyst deactivation is accelerated when the space-time velocity of liquid is too high. High temperature is conducive to the catalytic reforming of wood vinegar to produce hydrogen. When the temperature reaches 900 °C, the hydrogen yield is the highest. With the increase of cobalt content, the carbon deposition and hydrogen yield decrease. Therefore, when the liquid space velocity is 60 h⁻¹ and the temperature is 800 °C, the Ni-0.5Co/Al₂O₃ catalyst is most conducive to the hydrogen production experiment of wood vinegar.
- wood vinegar,
- hydrogen from reforming,
- nickel-based catalyst,
- carbon deposition
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