Citation: Ting-ting ZHANG, Chang-song ZHOU, Meng-chang ZHOU, Hao WU, Zhen ZHANG, Hong-min YANG. Study on the synergistic heterogeneous Fenton oxidation degradation of benzene containing waste gas using Fe doped UiO-66[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 220-227. doi: 10.19906/j.cnki.JFCT.2021013 shu

Study on the synergistic heterogeneous Fenton oxidation degradation of benzene containing waste gas using Fe doped UiO-66

School of Energy & Mechanical Engineering, Nanjing Normal University, Nanjing 210023, China

Corresponding author: Chang-song ZHOU, cszhou@njnu.edu.cn
Received Date: 29 September 2020
Revised Date: 9 November 2020

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The UiO-66 catalysts with different doping ratio of Fe were prepared by hydrothermal synthesis method in this study. The physicochemical properties of the catalysts were characterized by means of XRD, SEM and XPS. The benzene removal efficiency of the catalysts was investigated using a bench-scaled heterogeneous Fenton-like system device. The effects of Fe loading amount, H₂O₂concentration, superficial velocity and reaction temperature on benzene removal efficiency were studied. The results showed that the Fe doped UiO-66 was irregularly spherical and of high crystallinity. The highest benzene removal efficiency was obtained at 93% over the catalyst with 30% Fe loading. The EPR results proved that increasing Fe loading on UiO-66 evidently promoted the production of ·OH radicals, which promoted the degradation of benzene to a certain extent. The benzene removal efficiency decreased with the rise of temperature at higher range because H₂O₂ was unstable at high temperature.
- catalyst,
- benzene,
- heterogeneous Fenton,
- metal organic framework,
- volatile organic compounds
1. [1]
  TANG Ji-yun, ZHU Chao, ZHANG Hong-xin. Research on molecular sieve in the treatment of volatile organic compounds[J]. Appl Energy Technol,2018,,(9):46−49. doi: 10.3969/j.issn.1009-3230.2018.08.011
2. [2]
  JIA Yong-qin, ZHANG Xiao-jing. Molecular sieve supported CoO_x catalyst for catalytic oxidation of Benzene[J]. Environ Sci Technol,2018,41(9):28−32.
3. [3]
  MARIA L A, VIVIAN S M, VIVIAN S M, BRASILEIRO C, POLLYANA C R. Synthesis of mixed oxide Ti/Fe₂O₃ as solar light-induced photocatalyst for heterogeneous photo-Fenton like process[J]. J Photochem Photobiol, A, 2021, 404: 112873.
4. [4]
  KHAN N A, HASAN Z, JHUNG S H. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): A review[J]. J Hazard Mater,2013,244-245:444−456. doi: 10.1016/j.jhazmat.2012.11.011
5. [5]
  WU J H, XIA Q B, LI Z, PI Y H. Facilitation of the visible light-induced Fenton-like excitation of H₂O₂ via heterojunction of g-C₃N₄/NH₂-Iron terephthalate metal-organic framework for MB degradation[J]. Appl Catal B: Environ,2017,202:653−663. doi: 10.1016/j.apcatb.2016.09.073
6. [6]
  MA X C, LI L Q, CHEN R F, WANG C H, LI H L, WANG S B. Heteroatom-doped nanoporous carbon derived from MOF-5 for CO₂ capture[J]. Appl Surf Sci,2018,435:494−502. doi: 10.1016/j.apsusc.2017.11.069
7. [7]
  PAN Y, JIANG S S, XIONG W, LIU D R, LUO D. Supported CuO catalysts on metal-organic framework (Cu-UiO-66) for efficient catalytic wet peroxide oxidation of 4-chlorophenol in wastewater[J]. J Hazard Mater,2020,291:109703.
8. [8]
  GONZALEZ-OLMOS R, MARTIN M J, GEORGI A, KOPINKE F D, OLLER L, MALATO S. Fe-zeolites as heterogeneous catalysts in solar Fenton-like reactions at neutral pH[J]. Appl Catal B: Environ,2012,125:51−58. doi: 10.1016/j.apcatb.2012.05.022
9. [9]
  LI Yin-ying Study on Fe-based metal-organic framework heterogeneous Fenton catalyst for degradation of dyes[D]. Chongqing: Southwest University, 2019.
10. [10]
  SUN Q, LIU M, LI K Y, HAN Y T, ZUO Y, WANG J H, SONG C S, ZHANG G L, GUO X W. Controlled synthesis of mixed-valent Fe-containing metal organic framework for degradation of phenol under mild conditions[J]. Dalton Trans,2016,10:1039.
11. [11]
  CAVKA J H, JAKOBSEN S, OLSBYE U, GUILLOU N, LAMBERTI C, BORDIGA S, LILLERUD K P. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J]. J Am Chem Soc,2008,130(42):13850−1. doi: 10.1021/ja8057953
12. [12]
  WEN C Y, WANG C G, CHEN, L G, ZHANG X H, LIU Q Y, MA L L. Effect of hierarchical ZSM-5 zeolite support on direct transformation from syngas to aromatics over the iron-based catalyst[J]. Fuel,2019,244:492−498. doi: 10.1016/j.fuel.2019.02.041
13. [13]
  YU C L, DONG L F, CHEN F, LIU X Q, HUANG B C. Low-temperature SCR of NOx by NH3 over MnO_x/SAPO-34 prepared by two different methods: a comparative study[J]. Environ Technol,2017,38:1030−1042. doi: 10.1080/09593330.2016.1216170
14. [14]
  SANDRO B, OLIVER K, ARNO T, RODERIK A. The state of the art in selective catalytic reduction of NO_x by ammonia using metal-exchanged zeolite catalysts[J]. Catal Rev,2008,50:492−531. doi: 10.1080/01614940802480122
15. [15]
  NIE Ming-xing. Study on the Preparation of Iron-based Oxide Heterogenerous Fenton-like catalysts and Degradation of Tetracycline[D]. Hefei: University of Science and Technology of China, 2020.
16. [16]
  GUO L S, LI J, ZENG Y, KOSOL R, TSUBAKI N. Heteroatom doped iron-based catalysts prepared by urea self-combustion method for efficient CO₂ hydrogenation[J]. Fuel,2020,276:118102.
17. [17]
  SALAZAR-AGUILAR A D, VEGA G, CASAS J A, VEGA-DÍAZ S M, QUINTANILLA A. Direct hydroxylation of phenol to dihydroxybenzenes by H₂O₂ and Fe-based metal-organic framework catalyst at room temperature[J]. Catalysts,2020,10(2):172.
18. [18]
  YAMASHITA T, HAYES P. Erratum to "Analysis of XPS spectra of Fe²⁺ and Fe³⁺ ions in oxide materials"[J]. Appl Surf Sci,2008,254:2441−2449. doi: 10.1016/j.apsusc.2007.09.063
19. [19]
  GONG Z J, WEN F W, ZHAO Z W, LI B W. Combination of catalytic combustion and catalytic denitration on semi-coke with Fe₂O₃ and CeO₂[J]. Catal Today,2018,318:59−65.
20. [20]
  XU Y, AI X, ZHANG H. The mechanism of degradation of bisphenol A using the magnetically separable CuFe₂O₄/peroxymonosulfate heterogeneous oxidation process[J]. J Hazard Mater,2016,309:87−96. doi: 10.1016/j.jhazmat.2016.01.023
21. [21]
  CHEN H, ZHANG Z L, YANG Z L, YANG Q, LI B, BAI Z Y. Heterogeneous fenton-like catalytic degradation of 2,4-dichlorophenoxyacetic acid in water with FeS[J]. Chem Eng J,2015,273:481−489. doi: 10.1016/j.cej.2015.03.079
22. [22]
  WANG Y, LIU Y X, LIU Y. Elimination of nitric oxide using new Fenton process based on synergistic catalysis: Optimization and mechanism[J]. Chem Eng J,2019,372:92−98. doi: 10.1016/j.cej.2019.04.122
23. [23]
  XIN S S, LIU G C, MA X H, GONG J X, XIN Y J. High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO₂ for the degradation of tetracycline: Economical synthesis, catalytic performance and mechanism[J]. Appl Catal B: Environ, 2021, 280: 119386.
24. [24]
  GUO R T, PAN W G, ZHANG X B, REN J X, JIN Q, XU H J, WU J. Removal of NO by using Fenton reagent solution in a lab-scale bubbling reactor[J]. Fuel,2011,90(11):3295−3298. doi: 10.1016/j.fuel.2011.06.030
25. [25]
  LIU Y, WANG Y. Removal of gaseous hydrogen sulfide by a Photo-Fenton wet oxidation scrubbing system[J]. Energy Fuels,2019,33(11):10812−10819.
26. [26]
  ZHOU Chang-song. Experimental and mechanism study of elemental mercury removal from flue gas over iron-based Fenton-like catalysts[D]. Wuhan: Huazhong University of Science and Technology, 2016.
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