Citation: Xiong-chao LIN, Zhe SHENG, Ke-ke SHAO, De-ping XU, Yong-gang WANG. Influence of group component distribution of coal tar pitch on mesophase structure development of needle coke[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 151-159. doi: 10.19906/j.cnki.JFCT.2021008 shu

Influence of group component distribution of coal tar pitch on mesophase structure development of needle coke

School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

Corresponding author: Xiong-chao LIN, linxiongchao@163.com
Received Date: 28 August 2020
Revised Date: 5 October 2020
Accepted Date: 1 January 2020

Figures(9)

Group composition distribution of raw coal tar pitch is the key factor to determine quality of needle coke. The components of coal tar pitch were separated by ultrasonic solvent extraction. Effect of each group composition on mesophase characteristics was investigated. The group components were well blended to explore impact of different components on formation and development of mesophase structure. The results show that n-hexane soluble fraction (HS) is rich of aliphatic functional groups, and the excessive amount of HS fraction is not conducive in formation of large scale mesophase. Nevertheless, an appropriate amount of HS can maintain a proper lower viscosity in a long time range of the melting pitch system, which is significantly beneficial to growth and development of mesophase. Toluene insoluble substance (TI) is mainly consisted of dense cyclic aromatic hydrocarbon with high degree of polymerization. It can accelerate generation and development of mesophase sphere. However, excessive TI fraction can lead to generation of mosaic structure and reduce quality of needle coke. The green coke obtained from n-hexane insoluble and toluene soluble matters (HI-TS) demonstrate better optical anisotropy structure and is considered be the most suitable component for preparation of needle coke. The refined pitch with HS≈25%, HI-TS≈69%, and TI≈3%−8% can produce needle coke with well-developed mesophase structure and low thermal expansion coefficient.
- coal tar pitch,
- solvent extraction,
- composition,
- carbonization,
- needle coke
1. [1]
  HU Jian-hong, CHENG Xiang-lin, LI Guo-ning, WU Jian-jun, JI Wei, WANG Yong-gang, WANG Bai-chuan. Association behavior of coal tar pitch soluble components in toluene[J]. J Fuel Chem Technol,2014,42(7):774−778.
2. [2]
  TANG Xian-yi, WEI Xiao-hui, XU De-ping, ZHANG Hai-yong, HE Xin, XIONG Chu-an, TANG Han-ying. Removal of QI from medium-temperature coal tar pitch and preparation of needle coke through carbonization[J]. Chin J Mater Res,2016,30(6):448−455. doi: 10.11901/1005.3093.2015.685
3. [3]
  MOCHIDA I, OYAMA T, KORAI Y, FEI Y Q. Study of carbonization using a tube bomb: Evaluation of lump needle coke, carbonization mechanism and optimization[J]. Fuel,1988,67(9):1171−1181. doi: 10.1016/0016-2361(88)90033-6
4. [4]
  MOCHIDA I, KORAI Y, OYAMA T, NESUMI Y, TODO Y. Carbonization in the tube bomb leading to needle coke: I. Cocarbonization of a petroleum vacuum residue and a FCC-decant oil into better needle coke[J]. Carbon,1989,27(3):359−365. doi: 10.1016/0008-6223(89)90067-5
5. [5]
  ALVAEZ P, DIEZ N, SANTAMARIA R, BLANCO C, MENENDEZ R, GRANDA M. Novel coal-based precursors for cokes with highly oriented microstructures[J]. Fuel,2012,95:400−406. doi: 10.1016/j.fuel.2011.09.023
6. [6]
  LEE S, EOM Y, KIM B J, MOCHIDA I, YOON S H, KIM B C. The thermotropic liquid crystalline behavior of mesophase pitches with different chemical structures[J]. Carbon,2015,81:694−701. doi: 10.1016/j.carbon.2014.10.007
7. [7]
  MOCHIDA I, FEI Y Q, KORAI Y, OISHI T. Co-carbonization of ethylene tar pitch and coal tar pitch to form needle coke[J]. Fuel,1990,69(6):672−677. doi: 10.1016/0016-2361(90)90027-N
8. [8]
  MOCHIDA I, KORAI Y, ABE S, SAKANISHI A, TODO Y, OYAMA T. Co-carbonization properties of dewaxed FCC decant oils with low sulfur vacuum residue leading to production of needle coke[J]. J Jpn Petrol Inst,1990,33(6):367−372. doi: 10.1627/jpi1958.33.367
9. [9]
  MOCHIDA I, FEI Y Q, KORAI Y, FUJIMOTO K, YAMASHITA R. Carbonization in the tube bomb leading to needle coke: III. Carbonization properties of several coal-tar pitches[J]. Carbon,1989,27(3):375−380. doi: 10.1016/0008-6223(89)90069-9
10. [10]
  CHANG Y C, SOHN H J, KU C H, WANG Y G, KORAI Y, MOCHIDA I. Anodic performances of mesocarbon microbeads (MCMB) prepared from synthetic naphthalene isotropic pitch[J]. Carbon,2016,37(8):1285−1297.
11. [11]
  MENÉNDEZ R, GRANDA M, BERMEJO J. Relationships between pitch composition and optical texture of cokes[J]. Carbon,1997,35(4):555−562. doi: 10.1016/S0008-6223(97)00006-7
12. [12]
  MOCHIDA I, KORAI Y, KU C H, WATANABE F, SAKAI Y. Chemistry of synthesis, structure, preparation and application of aromatic-derived mesophase pitch[J]. Carbon,2000,38(2):305−328. doi: 10.1016/S0008-6223(99)00176-1
13. [13]
  YANG K S, KIM Y A, AN K H, YOON S H, SON T W, MOCHIDA I. Modification of naphthalene-derived mesophase pitch with benzoquinone[J]. Carbon,1997,35(7):923−928. doi: 10.1016/S0008-6223(97)00046-8
14. [14]
  LI M, LIU D, MEN Z W, LOU B, YU S T, DING J W, CUI W L. Effects of different extracted components from petroleum pitch on mesophase development[J]. Fuel,2018,222:617−626. doi: 10.1016/j.fuel.2018.03.011
15. [15]
  CHENG Xiang-lin, ZHA Qing-fang, ZHONG Jing-tao, HOU Bao-hua, GUO Yan-sheng. Influences of alkyl group on the formation of needle coke[J]. J Fuel Chem Technol,2009,37(2):166−169. doi: 10.3969/j.issn.0253-2409.2009.02.008
16. [16]
  XU Bin, LI Tie-hu, PAN Li-hui, FANG Qing-zhou. Influence of QI on thermal polymerization modification of coal-tar pitch[J]. J Fuel Chem Technol,2002,30(5):418−422. doi: 10.3969/j.issn.0253-2409.2002.05.007
17. [17]
  LIN X C, LI S Y, GUO F H, JIANG G C, CHEN X J, WANG Y G. High-efficiency extraction and modification on coal liquefaction residue using supercritical fluid with different types of solvents[J]. Energy Fuels,2016,30:3917−3928. doi: 10.1021/acs.energyfuels.6b00326
18. [18]
  YANG J Y, KIM B S, PARK S J, RHEE K Y, SEO M K. Preparation and characterization of mesophase formation of pyrolysis fuel oil-derived binder pitches for carbon composites[J]. Composites, Part B,2019,165:467−472. doi: 10.1016/j.compositesb.2019.01.102
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沈阳化工大学材料科学与工程学院沈阳 110142