Citation: Guang-Zeng CHENG, Shuai LIU, Huan-Lei WANG. Potential High-Performance Anode Material for Potassium Ion Batteries: Antimony[J]. Chinese Journal of Applied Chemistry, ;2021, 38(2): 170-180. doi: 10.19894/j.issn.1000-0518.200243 shu

Potential High-Performance Anode Material for Potassium Ion Batteries: Antimony

School of Materials Science and Engineering, Ocean University of China, Qingdao 266000, China

Corresponding author: Shuai LIU, liushuai6980@ouc.edu.cn Huan-Lei WANG, huanleiwang@ouc.edu.cn
Received Date: 13 August 2020
Accepted Date: 16 October 2020

Fund Project: the Shandong Provincial Key R & D Plan and the Public Welfare Special Program, China 2019GGX102038the Fundamental Research Funds for the Central Universities 201822008the Fundamental Research Funds for the Central Universities 201941010the Qingdao City Programs for Science and Technology Plan Projects 19-6-2-77-cg

Figures(7)

In recent years, with the increasing demand for energy storage devices, potassium ion batteries have attracted more and more attention. The physical and chemical properties of potassium is similar to those of lithium, and the reserve of potassium in the earth's crust is abundant, so potassium ion battery has a promising prospect in the field of energy storage. However, due to the fact that the actual capacity of electrode materials is far less than the theoretical capacity, the performance of potassium ion battery is still inadequate. Metallic antimony has a high theoretical capacity and is widely investigated as electrodes. However, too large volume change during charging-discharging process leads to the poor stability. The structural stability can be improved by controlling the morphology, alloying and introducing carbon framework. In this paper, the research progress of antimony materials as anodes for potassium ion batteries is introduced, and the application of antimony electrode is prospected.
- Potassium ion battery,
- Antimony anode,
- Alloying,
- Composite materials,
- Nanostructure
1. [1]
  PAN H, HU Y S, CHEN L. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage[J]. Energy Environ Sci, 2013,6(8):2338-2360. doi: 10.1039/c3ee40847g
2. [2]
  TAO L, YANG Y, WANG H. Sulfur-nitrogen rich carbon as stable high capacity potassium ion battery anode: performance and storage mechanisms[J]. Energy Storage Mater, 2020,27:212-225. doi: 10.1016/j.ensm.2020.02.004
3. [3]
  LU G, WANG H, ZHENG Y. Metal-organic framework derived N-doped CNT@porous carbon for high-performance sodium and potassium-ion storage[J]. Electrochim Acta, 2019,319:541-551. doi: 10.1016/j.electacta.2019.07.026
4. [4]
  FAN L, LIU Q, CHEN S. Potassium-based dual ion battery with dual-graphite electrode[J]. Small, 2017,13(30)1701011. doi: 10.1002/smll.201701011
5. [5]
  RAJAGOPALAN R, TANG Y, JI X. Advancements and challenges in potassium ion batteries: a comprehensive review[J]. Adv Funct Mater, 2020,30(12)1909486. doi: 10.1002/adfm.201909486
6. [6]
  WU X, CHEN Y, XING Z. Advanced carbon-based anodes for potassium-ion batteries[J]. Adv Energy Mater, 2019,9(21)1900343. doi: 10.1002/aenm.201900343
7. [7]
  SONG K, LIU C, MI L. Recent progress on the alloy-based anode for sodium-ion batteries and potassium-ion batteries[J]. Small, 20191903194.
8. [8]
  XIONG P, WU J, ZHOU M. Bismuth-antimony alloy nanoparticle@porous carbon nanosheet composite anode for high-performance potassium-ion batteries[J]. ACS Nano, 2019,14(1):1018-1026.
9. [9]
  KIM D S, BAE J, KWON S H. Synergistic effect of antimony-triselenide on addition of conductive hybrid matrix for high-performance lithium-ion batteries[J]. J Alloys Comp, 2020,828154410. doi: 10.1016/j.jallcom.2020.154410
10. [10]
  ZHAO Y, MANTHIRAM A. High-capacity, high-rate Bi-Sb Alloy anodes for lithium-ion and sodium-ion batteries[J]. Chem Mater, 2015,27(8):3096-3101. doi: 10.1021/acs.chemmater.5b00616
11. [11]
  WANG J, FAN L, LIU Z. In situ alloying strategy for exceptional potassium ion batteries[J]. ACS Nano, 2019,13(3):3703-3713. doi: 10.1021/acsnano.9b00634
12. [12]
  GAO H, NIU J, ZHANG C. A dealloying synthetic strategy for nanoporous bismuth antimony anodes for sodium ion batteries[J]. ACS Nano, 2018,12(4):3568-3577. doi: 10.1021/acsnano.8b00643
13. [13]
  ZHENG W, YU X, GUO Z. Magnetron sputtering deposition of MSb (M=Fe, Ni, Co) thin films as negative electrodes for Li-ion and Na-ion batteries[J]. Mater Res Express, 2019,6(5)056410. doi: 10.1088/2053-1591/ab00cd
14. [14]
  WANG S, XIONG P, GUO X. A stable conversion and alloying anode for potassium-ion batteries: a combined strategy of encapsulation and confinement[J]. Adv Funct Mater, 20202001588.
15. [15]
  GABAUDAN V, BERTHELOT R, STIEVANO L. Inside the alloy mechanism of Sb and Bi electrodes for K-Ion batteries[J]. J Phys Chem C, 2018,122(32):18266-18273. doi: 10.1021/acs.jpcc.8b04575
16. [16]
  FAN S, SUN T, RUI X. Cooperative enhancement of capacities in nanostructured SnSb/carbon nanotube network nanocomposite as anode for lithium ion batteries[J]. J Power Sources, 2012,201:288-293. doi: 10.1016/j.jpowsour.2011.10.137
17. [17]
  HUANG Z, CHEN Z, DING S. Multi-protection from nano channels and graphene of SnSb-graphene-carbon composites ensuring high properties for potassium-ion batteries[J]. Solid State Ionics, 2018,324:267-275. doi: 10.1016/j.ssi.2018.07.019
18. [18]
  YANG K, TANG J, LIU Y. Controllable synthesis of peapod-like Sb@C and corn-like C@Sb nanotubes for sodium storage[J]. ACS Nano, 2020,14(5):5728-5737. doi: 10.1021/acsnano.0c00366
19. [19]
  YUAN Y, JAN S, WANG Z. A simple synthesis of nanoporous Sb/C with high Sb content and dispersity as an advanced anode for sodium ion batteries[J]. J Mater Chem A, 2018,6(14):5555-5559. doi: 10.1039/C8TA00592C
20. [20]
  PHAM X M, NGO D T, LEH T T. A self-encapsulated porous Sb-C nanocomposite anode with excellent Na-ion storage performance[J]. Nanoscale, 2018,10(41):19399-19408. doi: 10.1039/C8NR06182C
21. [21]
  GABAUDAN V, TOUJA J, COT D. Double-walled carbon nanotubes, a performing additive to enhance capacity retention of antimony anode in potassium-ion batteries[J]. Electrochem Common, 2019,105106493. doi: 10.1016/j.elecom.2019.106493
22. [22]
  HAN Y, LI T, LI Y. Stabilizing antimony nanocrystals within ultrathin carbon nano sheets for high-performance K-ion storage[J]. Energy Storage Mater, 2019,20:46-54. doi: 10.1016/j.ensm.2018.11.004
23. [23]
  YI Z, LIN N, ZHANG W. Preparation of Sb nanoparticles in molten salt and their potassium storage performance and mechanism[J]. Nanoscale, 2018,10(27):13236-13241. doi: 10.1039/C8NR03829E
24. [24]
  LUO W, LI F, ZHANG W. Encapsulating segment-like antimony nanorod in hollow carbon tube as long-lifespan, high-rate anodes for rechargeable K-ion batteries[J]. Nano Res, 2019,12(5):1025-1031. doi: 10.1007/s12274-019-2335-6
25. [25]
  LIU S, FENG J, BIAN X. The morphology-controlled synthesis of a nanoporous-antimony anode for high-performance sodium-ion batteries[J]. Energy Environ Sci, 2016,9(4):1229-1236. doi: 10.1039/C5EE03699B
26. [26]
  WANG H, WU X, QI X. Sb nanoparticles encapsulated in 3D porous carbon as anode material for lithium-ion and potassium-ion batteries[J]. Mater Res Bull, 2018,103:32-37. doi: 10.1016/j.materresbull.2018.03.018
27. [27]
  AN Y, TIAN Y, CI L. Micron-sized nanoporous antimony with tunable porosity for high-performance potassium-ion batteries[J]. ACS Nano, 2018,12(12):12932-12940. doi: 10.1021/acsnano.8b08740
28. [28]
  LIANG L, XU Y, WANG C. Large-scale highly ordered Sb nanorod array anodes with high capacity and rate capability for sodium-ion batteries[J]. Energy Environ Sci, 2015,8(10):2954-2962. doi: 10.1039/C5EE00878F
29. [29]
  WANG Z M, YI Z, ZHONG M. Research progress of Sb based anode materials for lithium Ion batteries[J]. Chinese J Appl Chem, 2018,35(7):745-755.
30. [30]
  ZHANG Y J, ZHANG J F, DUAN J G. Research progress of Sb based anode materials for sodium ion batteries[J]. Materials Reports, 2020,34(11):11106-11113.
31. [31]
  LIU Q, FAN L, CHEN S. Antimony-graphite composites for a high-performance potassium-ion battery[J]. Energy Technol, 2019,7(10)1900634. doi: 10.1002/ente.201900634
32. [32]
  KO Y N, CHOI S H, KIM H. One-pot formation of Sb-carbon microspheres with graphene sheets: potassium-ion storage properties and discharge mechanisms[J]. ACS Appl Mater Interfaces, 2019,11(31):27973-27981. doi: 10.1021/acsami.9b08929
33. [33]
  YANG X, ZHANG R. High-capacity graphene-confined antimony nanoparticles as a promising anode material for potassium-ion batteries[J]. J Alloys Compd, 2020155191.
34. [34]
  CHENG N, ZHAO J, FAN L. Sb-MOFs derived Sb nanoparticles@porous carbon for high performance potassium-ion batteries anode[J]. Chem Commun, 2019,55(83):12511-12514. doi: 10.1039/C9CC06561J
35. [35]
  WANG H, WU X, QI X. Sb nanoparticles encapsulated in 3D porous carbon as anode material for lithium-ion and potassium-ion batteries[J]. Mater Res Bull, 2018,103:32-37. doi: 10.1016/j.materresbull.2018.03.018
36. [36]
  HAN C, HAN K, WANG X. Three-dimensional carbon network confined antimony nanoparticle anodes for high-capacity K-ion batteries[J]. Nanoscale, 2018,10(15):6820-6826. doi: 10.1039/C8NR00237A
37. [37]
  ZHENG J, YANG Y, FAN X. Extremely Stable antimony carbon composite anodes for potassium-ion batteries[J]. Energy Environ Sci, 2019,12(2):615-623. doi: 10.1039/C8EE02836B
38. [38]
  LIU D, YANG L, CHEN Z. Ultra-stable Sb confined into N-doped carbon fibers anodes for high-performance potassium-ion batteries[J]. Sci Bull, 2020,65(12):1003-1012. doi: 10.1016/j.scib.2020.03.019
39. [39]
  GUO S, LI H, LU Y. Lattice softening enables highly reversible sodium storage in anti-pulverization Bi-Sb alloy/carbon nanofibers[J]. Energy Storage Mater, 2020,27:270-278. doi: 10.1016/j.ensm.2020.02.003
40. [40]
  GABAUDAN V, BERTHELOT R, SOUGRATI M T. SnSb vs. Sn: improving the performance of Sn-based anodes for K-ion batteries by synergetic alloying with Sb[J]. J Mater Chem A, 2019,7(25):15262-15270. doi: 10.1039/C9TA03760H
41. [41]
  WANG Z, DONG K, WANG D. A nanosized SnSb alloy confined in N-doped 3D porous carbon coupled with ether-based electrolytes toward high-performance potassium-ion batteries[J]. J Mater Chem A, 2019,7(23):14309-14318. doi: 10.1039/C9TA03851E
42. [42]
  HAN J, ZHU K, LIU P. N-doped CoSb@C nanofibers as a self-supporting anode for high-performance K-ion and Na-ion batteries[J]. J Mater Chem A, 2019,7(44):25268-25273. doi: 10.1039/C9TA09643D
43. [43]
  ZHANG Y, LI M, HUANG F. 3D porous Sb-Co nanocomposites as advanced anodes for sodium-ion batteries and potassium-ion batteries[J]. Appl Surf Sci, 2020,499143907. doi: 10.1016/j.apsusc.2019.143907
1. [1]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
2. [2]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
6. [6]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
7. [7]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
10. [10]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
11. [11]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
12. [12]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
13. [13]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
14. [14]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
15. [15]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
16. [16]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
17. [17]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
18. [18]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042

Get Citation

PDF

XML

Metrics

PDF Downloads(106)
Abstract views(4754)
HTML views(1017)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142