Citation: Zhen-Jiang WU, Xiao-Wei HUO, Shou-Jun LIU, Song YANG. Preparation and Application of Resin-Free Color Pastes in Water-Based Pigment Systems[J]. Chinese Journal of Applied Chemistry, ;2021, 38(2): 212-219. doi: 10.19894/j.issn.1000-0518.200217 shu

Preparation and Application of Resin-Free Color Pastes in Water-Based Pigment Systems

Zhen-Jiang WU ^{1, 3} ,
Xiao-Wei HUO ² ,
Shou-Jun LIU ^{1, 2,,} ,
Song YANG ²

1.
Datong Inkall Chemicals Technology Co., Ltd, Datong 037500, China
2.
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
3.
Taiyuan Inkall Pen and Ink Technology Co., Ltd, Taiyuan 030032, China

Corresponding author: Shou-Jun LIU, 13303460889@163.com
Received Date: 21 July 2020
Accepted Date: 11 November 2020

Figures(6)

Gel ink is a thermodynamically unstable pigment suspension system. The choose of low-viscosity, high-stability color pastes is one of the important means to ensure the dispersion stability of the ink system. Based on this, using pigment carbon black and phthalocyanine blue as colorants, combined with hyperdispersant (EK43) and synergist (BM10), two resin-free color pastes suitable for gel ink systems were prepared. For the first time, from the perspective of the particle size of the color paste and the dispersion stability of the system, the dosage of EK43 and BM10 and the optimal grinding time were determined, and their physical and chemical properties, stability and writing performance were analyzed and tested. The results show that: adding 10.0% mass fraction of EK43 and 2.5% mass fraction of BM10 to the black paste, the grinding time is 90 min; the particle size and dispersion stability of the two color pastes reach the best when 8.0% EK43 and 2.0% BM10 are added to the blue paste and the grinding time is 120 min. The prepared resin-free color paste has high solid content, low viscosity, good storage stability, and strong tinting power. The gel ink formulated with it has good writing performance, and good centrifugal stability and heat stability.
- Resin-free color paste,
- Grinding time,
- Dispersion stability,
- Pigment solid content,
- Coloring power,
- Writing performance
1. [1]
  QIAN J J, CHEN A P, LIU Z X. The rheological characterization of the writing performance of carbon black gel ink[J]. Fine Chem, 2009,26(5):506-508.
2. [2]
  REN J, SHEN J, LU S C. Particle dispersion science and technology[M]. Beijing: Chem Industry Press, 2005: 7-8.
3. [3]
  EVANS S, PYSZCZEK E J. Surface modification of carbon black: US Patent, US20140000478[P]. 2015-6-27.
4. [4]
  PANCHOMPOO J, ALDOUS L, COMPTON R G. Size-effects in the chemical modification of carbon black nanoparticles with 4-nitroaniline[J]. New J Chem, 2010,34(11):2643-2653. doi: 10.1039/c0nj00400f
5. [5]
  SUN S J, ZHAN H J, ZHAO H Y. Research and preparation of water-based resin-free color paste system[J]. Paint Ind, 2011,41(1):33-37.
6. [6]
  WANG G C. Research on resin to improve the performance of waterborne coatings[J]. Shanxi Chem Ind, 2019(6):28-32.
7. [7]
  MU J Q, HAN F L, MA B. Influence of dispersant on the stability of carbon-based lubricant additives[J]. Lubric Seal, 2019,44(2):102-107.
8. [8]
  JIN Z Z. Research on resin-free color paste[J]. Paint Ind, 2009(9):61-66.
9. [9]
  LUO C L, HUANG L. Research on grinding and preparation methods of resin-free color paste[J]. Chem Manage, 2018(7):187-188.
10. [10]
  GUO J L, LIU S J, ZHANG R D. The influence of water-soluble alcohol on the performance of neutral ink[J]. Fine Chem, 2016,33(2):102-107.
11. [11]
  ZHANG X Y. Formula design and performance evaluation of neutral ink[D]. Taiyuan: Taiyuan University of Technology, 2019.
12. [12]
  LIU J, LU X P, WU M. Hyperdispersant and its application in pigment dispersion[J]. Shanghai Paint, 2009(1):34-36.
13. [13]
  MIAO Y, KONG L H, HUANG X D. Preparation of precipitation method of silica and study on filling SSBR/BR[J]. J Beijing Univ Chem Technol (Nat Sci Ed), 2019,46(2):33-39.
14. [14]
  QIAO X X, LI Y B. A brief talk on the influence of potassium carbonate on the control of carbon black oil absorption[J]. China Rubber, 2017(14):33-37.
15. [15]
  YAN F. Carbon black industrial research and design institute developed a method to improve the dispersibility of carbon black[J]. Rubber Plast Technol Equip, 2017(1):20-23.
16. [16]
  DIAO H L, LIU S J, WANG J H. Quick characterization of neutral ink stability[J]. Chinese Pen Making, 2007(1):25-31.
17. [17]
  DIAO H L, LIU S J. Research on the stability of neutral ink and its quick evaluation method[J]. Taiyuan Technol, 2006(12):49-51.
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
3. [3]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
4. [4]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
5. [5]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
6. [6]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
7. [7]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
8. [8]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
9. [9]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
10. [10]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
11. [11]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
12. [12]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
13. [13]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
14. [14]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
15. [15]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
16. [16]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
17. [17]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
18. [18]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
19. [19]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
20. [20]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036

Get Citation

PDF

XML

Metrics

PDF Downloads(48)
Abstract views(3744)
HTML views(831)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142