Citation: LI Jia-Min,  LUO Li-Jun,  BI Xiao-Ya,  LIU Xiao-Hong,  LI Li-Bo,  YOU Tian-Yan. Peroxidase-like Catalytic Mechanism of CeO2-based Nanozymes and Their Colorimetric Sensing Applications[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(5): 631-641. doi: 10.19756/j.issn.0253-3820.231024 shu

Peroxidase-like Catalytic Mechanism of CeO2-based Nanozymes and Their Colorimetric Sensing Applications

  • Corresponding author: LUO Li-Jun,  YOU Tian-Yan, 
  • Received Date: 20 January 2023
    Revised Date: 16 March 2023

    Fund Project: Supported by the National Natural Science Foundation of China (No. 22074055), the Innovation/Entrepreneurship Program of Jiangsu Province and Priority Academic Program Development of Jiangsu Higher Education Institutions (No. PAPD-2018-87) and the Jiangsu Province and Education Ministry Cosponsored Synergistic Innovation Center of Modern Agricultural Equipment (No. XTCX2008).

  • Over the past few decades, a multitude of artificial enzymes have been investigated. With the development of nanoscience, nanozymes have attracted widespread attention of researchers because they can solve the issues of insufficient activity of traditional artificial enzymes. As one of the most interesting and important rare earth oxides in catalysis, CeO2 exhibits excellent peroxidase-like activity due to its fast Ce4+ ↔ Ce3+ redox switch and the existence of related oxygen vacancies. However, the combination of CeO2 with other materials to form CeO2-based nanozymes is beneficial to improve the catalytic performance. This review introduced a variety of CeO2-based nanozymes, discussed their peroxidase-like catalytic mechanisms, kinetics, and colorimetric sensing applications. Finally, the current challenges and potential future directions of CeO2-based nanozymes were summarized.
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