Citation: XIA Zi-Wei, JIN Yu-Qin, ZHENG Jing, ZHANG Min, YIN Xue-Bo. Preparation of ZIF-90 Manganese Dioxide Nanosheet Composite and Its Application for Glutathione Detection[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(5): 892-900. doi: 10.19756/j.issn.0253-3820.221624 shu

Preparation of ZIF-90 Manganese Dioxide Nanosheet Composite and Its Application for Glutathione Detection

Institute of Frontier Medical Technology, College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: YIN Xue-Bo, xbyin@nankai.edu.cn
Received Date: 18 December 2022
Revised Date: 6 March 2023

Fund Project: Supported by the National Natural Science Foundation of China (No. 22174077)

ZIF-90-MnO₂ nanosheet composite was prepared by growing MnO₂ nanosheets on ZIF-90 at 55 °C with dissolved oxygen. ZIF-90 provided nucleation sites and support for the growth of MnO₂ nanosheets and thus improved the dispersion and oxidase activity of MnO₂ nanosheets. A colorimetric sensor based on the oxidase-like activity of ZIF-90-MnO₂ was constructed to detect glutathione (GSH) colorimetrically. Under the optimized experimental conditions, the detection limit of GSH was 0.30 μmol/L (3σ), the linear range was 1.25—30 μmol/L, and the whole detection was completed within 15 min. Coexisting substances in the serum samples did not interfere with the detection. The strategy of preparing ZIF-90-MnO₂ nanosheet composite under mild conditions was expected to extend the application of MnO₂ as an oxidase-like enzyme.
- Manganese dioxide,
- ZIF-90,
- Glutathione,
- Colorimetric assay
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