Citation: WANG Yue, HE Yi-Jin, QIAO Chen-Xi, HAO Yi, ZHANG Jun-Jie, LYU Dong-Mei, GAO Rui-Xia. Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(2): 259-268. doi: 10.19756/j.issn.0253-3820.221361 shu

Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water

1.
School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China;
2.
School of Pharmacy, Xi'an Jiaotong University, Xi'an 710061, China

Corresponding author: GAO Rui-Xia, ruixiagao@mail.xjtu.edu.cn
Received Date: 19 July 2022
Revised Date: 29 August 2022

Fund Project: Reusability

The cochineal hyperbranched polyglycidyl ether magnetic adsorbents (Fe₃O₄-HPG) were synthesized for adsorption of cochineal with glycidyl ether as functional monomer, cochineal as target, and Fe₃O₄ as carrier by a simple and ingenious synthesis method for the first time. The physical and chemical properties of the materials were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). These results showed that Fe₃O₄-HPG had uniform particle size, good magnetism, and stable crystal structure. At the same time, the kinetic adsorption, thermodynamic adsorption, and reusability of Fe₃O₄-HPG were investigated. The prepared materials had high adsorption capacity (106.06 mg/g), fast adsorption rate (60 min) and good reusability (Adsorption efficiency of 95.8% after reusing for 8 times). Moreover, combined with high performance liquid chromatography, the Fe₃O₄-HPG as adsorbents were successfully used to specifically recognize and detect cochineal in environmental water with recoveries over 94.6%.
- Reusability,
- Magnetic separation,
- Hyperbranched adsorbent,
- Cochineal,
- High adsorption performance
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沈阳化工大学材料科学与工程学院沈阳 110142