Citation: NIE Jia, XU Tong, LIU Qian, SUN Xu-Ping. Synthesis of Fluorescent Carbon Nitride Dots as Probe for Detection of Copper Ion[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(10): 1502-1510. doi: 10.19756/j.issn.0253-3820.221270 shu

Synthesis of Fluorescent Carbon Nitride Dots as Probe for Detection of Copper Ion

NIE Jia ^1,2 ,
XU Tong ^1,2 ,
LIU Qian ³ ,
SUN Xu-Ping ^1,,

1.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China;
2.
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China;
3.
Institute for Advanced Study, Chengdu University, Chengdu 610106, China

Corresponding author: SUN Xu-Ping, xpsun@uestc.edu.cn
Received Date: 29 May 2022
Revised Date: 25 June 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.22072015) and the Key Research Program from Science and Technology Department of Sichuan Province, China (No.2020YFG0091).

Fluorescent probes have attracted a lot of attention because of their high accuracy and rapid visualization of heavy metals. Carbon nitride dots show potential applications in ion detection, due to their metal-free, water solubility, low toxicity, ease of preparation and high quantum yield. In this work, a carbon nitride dot fluorescent probe was prepared using ethanediamine and CCl₄, and Cu²⁺ could burst the fluorescence of the probe, based on which a Cu²⁺ fluorescence detection method was established. The linear detection range was 2.0-10.0 μmol/L, and the detection limit (S/N=3) was as low as 0.058 μmol/L. When this probe was used for the determination of Cu²⁺ in tap water, lake and wastewater, the recoveries were in the range of 91.5%-105.3%, indicating the practicality of this method. The fluorescence test paper constructed based on carbon nitride dots with a detection limit as low as 0.5 μmol/L provided an alternative solution for the real-time detection of Cu²⁺ in the field.
- Copper ion,
- Carbon nitride dots,
- Fluorescent probe,
- Test paper
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