Citation: WANG Li-Xue, TIAN Shi-Si, SONG Xi-Lin, LI Wen-Jie, LI Hui-Min, ZHAO Ya-Bin. Analysis of Fatty Acid Components in Fingerprint Residues by Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(10): 1542-1550. doi: 10.19756/j.issn.0253-3820.221246 shu

Analysis of Fatty Acid Components in Fingerprint Residues by Gas Chromatography-Mass Spectrometry

WANG Li-Xue ^1,2 ,
TIAN Shi-Si ¹ ,
SONG Xi-Lin ¹ ,
LI Wen-Jie ¹ ,
LI Hui-Min ¹ ,
ZHAO Ya-Bin ^1,3,,

1.
Academy of Forensic Science, People's Public Security University of China, Beijing 100038, China;
2.
Anhui Public Security Education Research Institute, Hefei 230031, China;
3.
Public Safety and Behavioral Science Laboratory, People's Public Security University of China, Beijing 100038, China

Corresponding author: ZHAO Ya-Bin, zhaoyb04@gmail.com
Received Date: 17 May 2022
Revised Date: 15 July 2022

Fund Project: Supported by the Science and Technology Foundation of Ministry of Public Security of China (No.2021JSM01) and the Basic Research Project of People's Public Security University of China (No.2021JKF219).

As an important trace evidence, fingerprints are widely used in personal identification and disclosure of criminal acts at the crime scene. Traditional fingerprint studies mainly focus on morphological analysis, while the in-depth exploration of its chemical constituents has always been neglected. In comparison, the chemical analysis of fingerprint substances can better improve the sensitivity and scientificity of fingerprint inspection technique. In this work, by taking the fatty acid in the fingerprint substance as the target, a new method was explored to measure the fatty acid by gas chromatography-mass spectrometry and applied to the analysis of real fingerprint samples. Experiment results showed that when the concentration of hydrochloric acid/methanol solution was 5% (V/V), the derivative temperature was 50℃, the derivative time was 20 min, and the derivative reagent amount was 400 μL, the fatty acid components in fingerprint residues could be detected more accurately. On this basis, the method was applied to the detection of lipid composition in real fingerprint samples, which identified the standard detection process for fingerprint samples and proved a quite obvious individual difference in lipid composition in fingerprint residues. The lipid composition of four fingerprints left by 2 volunteers on the same day was analyzed and the main components with 99.7% of the cumulative variance contribution rate by employing the principal component analysis method was retained, which demonstrated a strong correlation between the lipid composition of these fingerprints, further proving the stability and reproducibility of the fingerprint lipid composition detection method. This work might lay a research foundation for further exploration of employing fingerprint substances to identify individuals.
- Fatty acids,
- Fingerprint,
- Gas chromatography-mass spectrometry
1. [1]
2. [2]
3. [3]
  GIROD A, RAMOTOWSKI R, WEYERMANN C. Forensic Sci. Int., 2012, 223(1-3):10-24.
4. [4]
  CADD S, IALAM M, MANSON P, BLEAY S. Sci. Justice, 2015, 55(4):219-238.
5. [5]
  RAMOTOWSKI R S, LEE H C, GAENSSLEN R E. Composition of Latent Print Residues. Advanced in Fingerprint Technology.Boca Raton:CRC Press, 2001:63-104.
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
  ASANO K G, BAYNE C K, HORSMAN K M, BUCHANAN M V. J. Forensic Sci., 2002, 47(4):805-807.
17. [17]
  ARCHER N E, CHARLES Y, ELLIOTT J A, JICKELLS S. Forensic Sci. Int., 2005, 154(2):224-239.
18. [18]
  CROXTON R S, BARON M G, BUTLER D, KENT T, SEARS V G. J. Forensic Sci., 2006, 51(6):1329-1333.
19. [19]
  CROXTON R S, BARON M G, BUTLER D, KENT T, SEARS V G. Forensic Sci. Int., 2010, 199(1-3):93-102.
20. [20]
  GIROD A, WEYERMANN C. Forensic. Sci. Int., 2014, 238(5):68-82.
21. [21]
  GIROD A, SPYRATOU A, HOLMES D, WEYERMANN C. Sci. Justice, 2016, 56(3):165-180.
22. [22]
  MICHALSKI S, SHALER R, DORMAN F L. J. Forensic Sci., 2013, 58(SI):S215-S220.
23. [23]
  CADD S J, MOTA L, WERKMAN D, IALAM M, ZUIDBERG M, DE PUIT M. Anal. Methods, 2015, 7(3):1123-1132.
24. [24]
  PLEIK S, SPENGLER B, URBACH D, LUHN S, KIRSCH D. J. Am. Soc. Mass Spectrom., 2016, 27(9):1565-1574.
25. [25]
  KIM Y, CHOI W, CHOI E J, JEON B, KIM J, PARK G H, HUANG Y, WUFUER M, JIN X, KIM M O, XU L, PIAO Y L, PARK J H, KIM W K, CHOI T H. J. Anal. Sci. Technol., 2019, 10(1):29.
26. [26]
27. [27]
1. [1]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
2. [2]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
3. [3]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
7. [7]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
8. [8]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
9. [9]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
10. [10]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
11. [11]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
12. [12]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
13. [13]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
14. [14]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
15. [15]
  Zhenjun Mao , Haorui Gu , Haiyan Che , Xufeng Lin . Exploration on Experiment Teaching of UHPLC-IC Based on Valve Switching Method. University Chemistry, 2024, 39(4): 81-86. doi: 10.3866/PKU.DXHX202311013
16. [16]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
17. [17]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
18. [18]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
19. [19]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
20. [20]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(534)
HTML views(108)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142