Citation: WU Mian-Yuan, YU Yan-Chao, YOU Jun, WU Wen-Ju. Construction of Fluorescence Sensor for Detection of Glyphosate Based on Copper Ion[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(1): 130-138. doi: 10.19756/j.issn.0253-3820.221213 shu

Construction of Fluorescence Sensor for Detection of Glyphosate Based on Copper Ion

WU Mian-Yuan ^1,2 ,
YU Yan-Chao ^1,, ,
YOU Jun ¹ ,
WU Wen-Ju ¹

1.
School of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, China;
2.
Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China

Corresponding author: YU Yan-Chao, yychao136@163.com
Received Date: 4 May 2022
Revised Date: 6 August 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.21908034) and the Natural Science Foundation of Heilongjiang Province, China (No.LH2021H001).

A novel fluorescent probe CPS based on coumarin-derived acylhydrazone was designed and synthesized by using 7-diethylamino coumarin as report group. The results showed that probe CPS had obviously "On-Off" fluorescence response to Cu²⁺ in the methanol solution, and the stoichiometry of CPS-Cu²⁺ complex was estimated to be 2∶1. Meanwhile, a fluorescence sensor based on the complex CPS-Cu²⁺ showed high selectivity and sensitivity towards glyphosate, and the detection limit of glyphosate was 64.8 nmol/L (10.95 ng/mL). The mechanism of fluorescence sensor to detect glyphosate was speculated through Job's plot, molar ratio method and mass spectrometry. In addition, the applicability of fluorescence sensor in detection of glyphosate was verified by the standard recovery tests in practical water samples.
- Fluorescence sensor,
- Coumarin-derived acylhydrazone,
- Copper ion,
- Glyphosate
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