Citation: ZHANG Xin, GAO Yan-Fang. Molybdenum Disulfide Nanozymes for Colorimetric Determination of Hydrogen Peroxide[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(10): 1491-1501. doi: 10.19756/j.issn.0253-3820.221137 shu

Molybdenum Disulfide Nanozymes for Colorimetric Determination of Hydrogen Peroxide

ZHANG Xin ,
GAO Yan-Fang ^,

College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: GAO Yan-Fang, yf_gao@imut.edu.cn
Received Date: 17 March 2022
Revised Date: 27 July 2022

Fund Project: Supported by the Joint Funds of Inner Mongolia Autonomous Region, China (No.2021LHMS02002).

Molybdenum disulfide nanosheets (MoS₂ NSs) were prepared by a simple one-step hydrothermal method, and their structure and morphology were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscope (TEM). In the presence of hydrogen peroxide (H₂O₂), the obtained MoS₂ NSs could catalyze the oxidation of colorless 3,3',5,5'-tetramethylbenzidine (TMB) into blue oxidized products (oxTMB). On this basis, a colorimetric analysis method for determination of H₂O₂ concentration was established. The effects of color reaction conditions of MoS₂ NSs-TMB-H₂O₂ on peroxidase-like activity of MoS₂ NSs were investigated, and the steady-state kinetic analysis was carried out. The results showed that the enzymatic reaction of MoS₂ NSs using TMB and H₂O₂ as reaction substrates followed the typical Michaelis-Menten kinetic model. The linear range for colorimetric determination of H₂O₂ was 10-50 μmol/L, with a limit of detection (LOD, S/N=3) of 1.0 μmol/L. The established method was used in detection of H₂O₂ in milk samples and the recoveries of H₂O₂ spiked in milk were 92.4%-106.9%, showing good practicability.
- Molybdenum disulfide,
- Nanozyme,
- Peroxidase-like activity,
- Hydrogen peroxide,
- Colorimetric determination
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