Citation: LI Yue, ZHANG Guo-Xia, CAI Zhao-Qing, QIU Han-Xun, WANG Zheng. Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(9): 1384-1390. doi: 10.19756/j.issn.0253-3820.221100 shu

Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil

LI Yue ^1,2 ,
ZHANG Guo-Xia ² ,
CAI Zhao-Qing ^2,3 ,
QIU Han-Xun ^1,, ,
WANG Zheng ^2,3,,

1.
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China;
2.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China;
3.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: QIU Han-Xun, WANG Zheng,
Received Date: 25 February 2022
Revised Date: 26 May 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.E27GJ616), the Technical Innovation Project of Instrument and Equipment Function Development of Chinese Academy of Sciences (No. E07YQ7170G) and the Shanghai Technical Platform for Testing and Characterization on Inorganic Materials (No.19DZ2290700).

Rare earth pollution in soil affects plant growth and accumulates in animals and humans through the food chain, and causes serious environmental and human health issues. To take effective measures to control the rare earth pollution, it is necessary to detect the content of rare earth elements in soil. Laser-induced breakdown spectroscopy (LIBS) has many advantages including in-situ, non-destructive, real-time and multi-element simultaneous analysis for solid samples such as soil. However, the sensitivity of this technique is low, which limits its application in the quantitative analysis of trace elements. In this work, a new method utilizing the combination of atmospheric pressure glow discharge (APGD) and cylindrical confinement (CC) was proposed to improve the detection sensitivity of laser-induced breakdown spectroscopy, which was applied to determination of Y, La, Eu, Yb and Lu rare earth elements in soil. The results showed that the detection sensitivity of LIBS for Y, La, Eu, Yb and Lu were enhanced by 11.6, 9.3, 7.9, 8.2 and 7.6 times by APGD and CC, respectively. To verify the accuracy of the proposed system, it was applied to the detection of soil certified reference materials and an unknown soil sample, and the relative errors between the detection values of this work and those of ICP-OES were 1.5%-8.6% and 1.8%-7.0%, respectively.
- Laser-induced breakdown spectroscopy,
- Atmospheric pressure glow discharge,
- Soil,
- Rare earth elements
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