Citation: RUAN Li-Ting, HE Shao-Ying, ZHAO Wan, CAO Hong-Shuai, XU Zhi-Ai, ZHANG Wen. Cerium Vanadate-based Peroxidase-like Nanozyme for Glucose and Total Antioxidant Capacity Assay[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(9): 1319-1327. doi: 10.19756/j.issn.0253-3820.221099 shu

Cerium Vanadate-based Peroxidase-like Nanozyme for Glucose and Total Antioxidant Capacity Assay

School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China

Corresponding author: ZHANG Wen, wzhang@chem.ecnu.edu.cn
Received Date: 24 February 2022
Revised Date: 13 April 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.22174047).

The cerium vanadate (CeVO₄)-based nanozyme was synthesized through a hydrothermal synthesis method with arginine as the stabilizer. Due to the change of stabilizer, the ratio of Ce^Ⅲ to Ce^Ⅳ in CeVO₄ changed and thus allowed that the nanozyme showed nanoparticle morphology, which was different from that of nanorod prepared with EDTA as stabilizer. In the reaction system of 3,3',5,5'-tetramethylbenzidine (TMB) and hydrogen peroxide (H₂O₂), the CeVO₄-based nanozyme first catalyzed H₂O₂ to produce hydroxyl radical (·OH), which could oxidize TMB and thus resulted in a colour change of solution from colourless to blue, proving that CeVO₄ prepared with arginine had strong peroxidase-like activity and the generation of ·OH accounted for the outstanding peroxidase-like properties. Based on these features, a colorimetric method was developed for detecting H₂O₂, glucose and antioxidants. This study not only provided a new direction for the research of CeVO₄-based nanozyme, but also developed a fast and simple method for total antioxidant capacity (TAC) assay.
- Cerium vanadate,
- Nanozyme,
- Colorimetry,
- Glucose,
- Total antioxidant capacity
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