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Citation: HU Ming-Jiang,  LYU Chun-Wang,  ZHAO Li-Xia,  WANG Xu-Rong,  SONG Yan-Ping,  HENG Li-Jun. Heterojunction Bi2O3-TiO2 Nanofiber as Cataluminescence Material for Detection of Toluene[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(7): 1103-1111. doi: 10.19756/j.issn.0253-3820.221062 shu

Heterojunction Bi2O3-TiO2 Nanofiber as Cataluminescence Material for Detection of Toluene

  • School of Energy and Building Environmental Engineering, Henan University of Urban Construction, Pingdingshan 467036, China

  • Corresponding author: HU Ming-Jiang, hu_mingjiang@163.com
  • Received Date: 2 February 2022
    Revised Date: 24 April 2022

    Fund Project: Supported by the Science and Technology Foundation of He'nan Province, China (No.212102210199).

  • Bi2O3-TiO2 nanofibers (NFs) were synthesized by electrospinning method, and a geterojunction cataluminescence toluene gas sensor was thus designed by depositing Bi2O3-TiO2 NFs onto the cylindrical ceramic heating rod surface as cataluminescence material by dip-coating method. The crystalline phase and microstructure of Bi2O3-TiO2 NFs were displayed using X-ray diffraction and scanning electron microscope, and the cataluminescence mechanism and electrochemical characteristic of Bi2O3-TiO2 NFs in detection of toluene were analyzed by UV-Vis spectrometry, X-ray photoelectron spectroscopy and Fourier infrared spectroscopy (FT-IR). Density functional theory (DFT) was used to calculate the charge density and differential charge density of atoms in Bi2O3-TiO2 NFs heterojunction, and the sensitization mechanism of sensor was further proposed for detecting toluene gas. Under the optimal conditions including 450 nm of wavelength, 200 mL/min of flow rate and at 250℃, there was a good relationship between the CTL intensity of Bi30 toluene gas sensor and the toluene concentration in the range of 0.1-200 μg/m3. The detection limit was 0.1 μg/m3 (S/N=10), the RSD was 1.81%, and the dynamic response time and recover time of toluene gas sensor were 7.2 s and 9.4 s respectively. This study provided a feasible strategy for rapid and efficient detection of toluene, as well as a new sensing platform for detection of volatile organic compounds.
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