Citation: WEI Liang, HUANG Xin-Long, WANG Yan-Li, YANG Jing, YAN Fei-Yan, NING De-Jiao, TANG Li, LUO Li-Hong, WEI Yu-Ning, YA Yu. Preparation of Hierarchically Porous Carbon Using Different Activators and Its Electrochemical Sensing of Dihydroxybenzene Isomers[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(6): 899-911. doi: 10.19756/j.issn.0253-3820.221048 shu

Preparation of Hierarchically Porous Carbon Using Different Activators and Its Electrochemical Sensing of Dihydroxybenzene Isomers

WEI Liang ¹ ,
HUANG Xin-Long ¹ ,
WANG Yan-Li ² ,
YANG Jing ¹ ,
YAN Fei-Yan ² ,
NING De-Jiao ² ,
TANG Li ² ,
LUO Li-Hong ² ,
WEI Yu-Ning ² ,
YA Yu ^2,,

1.
College of Chemistry and Materials Science, Nanning Normal University, Nanning 530001, China;
2.
Institute for Agricultural Product Quality Safety and Testing Technology, Guangxi Academy of Agricultural Sciences, Nanning 530007, China

Corresponding author: YA Yu, yayu1026@163.com
Received Date: 24 January 2022
Revised Date: 30 March 2022

Fund Project: Supported by the National Natural Science Foundation of China(No. 21862004), the Natural Science Foundation of Guangxi, China(Nos. 2018GXNSFAA281230, 2018GXNSFAA281228), the Guangxi Agricultural Science and Technology Union Project(No. 202216), the Dominant Research Team Project of Guangxi Academy of Agricultural Sciences(No. 2021YT136), and the Innovation Project of Guangxi Graduate Education(No.YCSW2020193)

The hierarchically porous carbon materials were prepared with chitosan(CS) as carbon source, and NaCl, NaOH and Na₂CO₃ as activators. The morphology, porous structure, specific surface area and pore size distribution of the prepared carbon materials were characterized by scanning electron microscopy, X-ray diffraction, Raman spectrum and nitrogen adsorption-desorption isotherms,respectively. And the electrochemical properties of different carbon materials-modified electrode were studied by electrochemical techniques. Thus, structure-activity relationship between the morphology,structural and physicochemical parameters of different carbon materials and their electrochemical sensing properties were explored. The results showed that the hierarchically porous carbon material(CS-Na₂CO₃,prepared using Na₂CO₃ as activator) modified electrode had larger electrochemical active area, faster electron transfer rate and better electrocatalytic performance for three dihydroxybenzene isomers. A highperformance electrochemical sensing platform for simultaneous determination of hydroquinone, catechol and resorcinol was constructed based on the signal enhancement effect of CS-Na₂CO₃. The linear ranges for simultaneous determination of hydroquinone, catechol and resorcinol were 0.050-1.5 μmol/L,0.050-1.5 μmol/L and 0.50-15 μmol/L, and the detection limits (3σ) were calculated to be 0.012, 0.017 and 0.29 μmol/L, respectively. The prepared sensing platform demonstrated good accuracy in detection of dihydroxybenzene isomers in river water samples.
- Activators,
- Hierarchically porous carbon materials,
- Electrochemical sensing,
- Structure-activity relationship,
- Dihydroxybenzene isomers
1. [1]
  WANG N Y, YANG Z J, YANG D H, ZHAO L, SHI X R, YANG G, HAN B H. ACS Appl. Mater. Interfaces, 2021, 13(7):8832-8843.
2. [2]
  ZHONG R, ZHI C, WU Y, LIANG Z, TABASSUM H, ZHANG H, QIU T, GAO S, SHI J, ZOU R. Chin. Chem.Lett., 2020, 31(6):1588-1592.
3. [3]
  WU X, LI H, YANG X, WANG X, MIAO Z, ZHOU P, ZHOU J, ZHUO S. Electrochim. Acta, 2021, 368:137610.
4. [4]
  YI Y, WANG P, FAN G, WANG Z, CHEN S, XUE T, WEN Y. ACS Sustainable Chem. Eng., 2020, 8(26):9937-9946.
5. [5]
  WU W, LIU Y, LIU D, CHEN W, SONG Z, WANG X, ZHENG Y, LU N, WANG C, MAO J, LI Y. Nano Res., 2021, 14(4):998-1003.
6. [6]
  LIU Z, WANG L, YANG W. Chin. Chem. Lett., 2021, 32(9):2919-2922.
7. [7]
  HUO S, ZHAO Y, ZOMG M, LIANG B, ZHANG X, KHAN I U, SONG X, LI K. J. Mater. Chem. A, 2020, 8(5):2505-2517.
8. [8]
  DÍEZ N, FERRERO G A, SEVILLA M, FUERTES A B. J. Mater. Chem. A, 2019, 7(23):14280-14290.
9. [9]
10. [10]
  WEI L, HUANG X, ZHANG X, YANG X, YANG J, YAN F, YA Y. Anal. Methods, 2021, 13(9):1110-1120.
11. [11]
12. [12]
  RIAZ M A, YUAN Z, MAHMOOD A, LIU F, SUI X, CHEN J, HUANG Q, LIAO X, WEI L, CHEN Y. Sens.Actuators, B, 2020, 319:128243.
13. [13]
  MENG S, MO Z, LI Z, GUO R, LIU N. Mater. Chem. Phys., 2020, 246:122830.
14. [14]
  GUO N, LI M, SUN X, WANG F, YANG R. Green Chem., 2017, 19(11):2595-2602.
15. [15]
  ZHU S, LI J J, HE C N, ZHAO N Q, LIU E Z, SHI C S, ZHANG M. J. Mater. Chem. A, 2015, 3(44):22266-22273.
16. [16]
  WAN L, HU S Y, LIU J X, CHEN D Q, LIU S S, XIAO R, ZHANG Y, CHEN J, DU C, XIE M J. Ionics, 2020, 26:2549-2561.
17. [17]
  SENTHIKUMAR S T, PARK S O, KIM J S, HWANG S M. J. Mater. Chem. A, 2017, 5(27):14174-14181.
18. [18]
  SEVILLA M, FUERTES A B. J. Mater. Chem. A, 2013, 1(44):13738-13741.
19. [19]
20. [20]
  ZHANG S, CUI Y, WU B, SONG R, SONG H, ZHOU J, CHEN X, LIU J, CAO L. RSC Adv. 2014, 4(1):505-509.
21. [21]
  QIAO Z, HWANG S, LI X, WANG C, SAMARAKOOND W, KARAKALOSE S, LI D, CHEN M, HE Y, WANG M, LIU Z, WANG G, ZHOU H, FENG Z, SU D, SPENDELOW J S, WU G. Energy Environ. Sci., 2019, 12(9):2830-2841.
22. [22]
  SHAO D, WANG C, WANG L, GUO X, GUO J, ZHANG S, LU Y. J. Alloys Compd., 2021, 863:158682.
23. [23]
  LI H, LV N, LI X, LIU B, FENG J, REN X, GUO T, CHEN D, STODDART J F, GREF R, ZHANG J. Nanoscale, 2017, 9(22):7454-7462.
24. [24]
  XIAO X, LI X, WANG Z, YAN G, GUO H, HU Q, LI L, LIU Y, WANG J. Appl. Catal., B, 2020, 265:118603.
25. [25]
  RANDLES J E B. Trans. Faraday Soc., 1948, 44:322-327.
26. [26]
  SEVCIK A. Collect. Czech. Chem. Commun., 1948, 13:349-377.
27. [27]
  YANG S, YANG M, YAO X, FA H, WANG Y, HOU C, Sens. Actuators, B, 2020, 320:128294.
28. [28]
  ANU PRATHAP M U, SATPATI B, SRIVASTAVA R. Sens. Actuators, B, 2013, 186:67-77.
29. [29]
  ZHANG C J, HAN M M, YU L L, QU L B, LI Z H. J. Electroanal. Chem., 2021, 890:115232.
30. [30]
  ATTA N F, GALAL A, EL-GOHARY A R M. J. Hazard. Mater., 2020, 388:122038.
31. [31]
  HUANG L L, CAO Y Y, DIAO D F. Sens. Actuators, B, 2020, 305:127495.
32. [32]
  DENG M, LIN S R, BO X J, GUO L P. Talanta, 2017, 174:527-538.
33. [33]
  ZHANG T T, GUO H, YANG M, SUN L, ZHANG J Y, WANG M Y, YANG F, WU N, YANG W. Microchem. J., 2022, 175:107139.
34. [34]
  YIN D D, LIU J, BO X J, GUO L P. Anal. Chim. Acta, 2020, 1093:35-42.
1. [1]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
2. [2]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
3. [3]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
4. [4]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
5. [5]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
6. [6]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
7. [7]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
8. [8]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
9. [9]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
10. [10]
  Xiaolei Jiang , Fangdong Hu . Exploring the Mirror World in Organic Chemistry: the Teaching Design of “Enantiomers” from the Perspective of Curriculum and Ideological Education. University Chemistry, 2024, 39(10): 174-181. doi: 10.3866/PKU.DXHX202402052
11. [11]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
12. [12]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
13. [13]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
16. [16]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
17. [17]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
18. [18]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
19. [19]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(687)
HTML views(133)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142