Citation: WU Yue, WANG Li, WANG Xiao-Nan, YAN Xiao-Qing. Amino-functionalized Nano Fe₃O₄ Adsorbent for Magnetic Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons from Environment Water Sample[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(7): 1093-1102. doi: 10.19756/j.issn.0253-3820.210848 shu

Amino-functionalized Nano Fe₃O₄ Adsorbent for Magnetic Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons from Environment Water Sample

Department of Public Health Laboratory Sciences, School of Public Health, Shanxi Medical University, Taiyuan 030001, China

Corresponding author: YAN Xiao-Qing, yanxiaoqing83@163.com
Received Date: 18 November 2021
Revised Date: 15 January 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.81502851) and the Startup Foundation for Doctors of Shanxi Medical University (No.055235).

The amino functionalized magnetic nano adsorbent (MNPs-NH₂) was prepared by solvothermal method for magnetic solid phase extraction (MSPE) of polycyclic aromatic hydrocarbons (PAHs) in aqueous medium in this work. The experimental results showed that the adsorbent could selectively adsorb high molecular weight PAHs with 4-6 benzene rings. The results of molecular simulation calculations and comparative experiments with other adsorbents showed that the amine groups on the surface of the adsorbents could not only promote the good dispersion of the adsorbent in water, but also enhance the adsorption of PAHs through hydrogen bonding. The MSPE-high performance liquid chromatography-fluorescence detection (HPLC-FLD) method for high molecular weight PAHs in water was established by optimizing various parameters affecting the extraction efficiency. In the linear range of 0.008-20 ng/mL, the recoveries of high molecular weight PAHs at two spiking concentration levels (1 ng/mL and 10 ng/mL) were 59.7%-99.0%, the relative standard deviations were 1.7%-9.0%, the limits of detection were 0.002-0.02 ng/mL, and the limits of quantification were 0.004-0.12 ng/mL. This method could be applied to the detection of high molecular weight PAHs in environmental water samples.
- Amino-functionalization,
- Magnetic solid phase extraction,
- Polycyclic aromatic hydrocarbons,
- Hydrogen bond
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Amino-functionalized Nano Fe₃O₄ Adsorbent for Magnetic Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons from Environment Water Sample