Citation: DING Yi, DIAO Quan, LIU Dong, LIU An-fei, JIAO Ming-li, ZHU Gen-xing. Synthesis of Graphene Quantum Dots and Application in Gas Sensing[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(4): 495-505. doi: 10.19756/j.issn.0253-3820.210843 shu

Synthesis of Graphene Quantum Dots and Application in Gas Sensing

DING Yi ¹ ,
DIAO Quan ^1,, ,
LIU Dong ² ,
LIU An-fei ¹ ,
JIAO Ming-li ^1,, ,
ZHU Gen-xing ¹

1.
School of Materials & Chemical Engineering, Zhongyuan University of Technology, Zhengzhou 450007, China;2 School of Agricultural Equipment Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: DIAO Quan, JIAO Ming-li,
Received Date: 17 November 2021
Revised Date: 20 January 2022

Fund Project: Supported by the National Natural Science Foundation of China (Nos. 61703446, 51973246)

Graphene quantum dots(GQDs), as a kind of zero-dimensional carbon nano material, not only have excellent properties of graphene, but also have quantum confinement effect and boundary effect. GQDs with different nano-size can be obtained by various preparation methods. The surface of GQDs has abundant functional groups, which can be further functionalized by compounding with other materials to meet the detection requirements of different gases and broaden its application range in gas sensing. In this review, the preparation methods of GQDs and their applications in gas sensing are introduced. In addition, the application prospect and development direction of GQDs in gas sensing are also prospected.
- Graphene quantum dots,
- Synthesis methods,
- Gas sensors,
- Review
1. [1]
  YAN Y, GONG J, CHEN J, ZENG Z, HUANG W, PU K, LIU J, CHEN P. Adv. Mater., 2019, 31(21):1808283.
2. [2]
  ABBAS A, MARIANA L T, PHAN A N. Carbon, 2018, 140:77-99.
3. [3]
  GHAFFARKHAH A, HOSSEINI E, KAMKAR M, SEHAT A A, DORDANIHAGHIGHI S, ALLAHBAKHSH A,VAN DER KUUR C, ARJMAND M. Small, 2022, 18(2):2102683.
4. [4]
  ZHENG X T, ANANTHANARAYANAN A, LUO K Q, CHEN P. Small, 2015, 11(14):1620-1636.
5. [5]
6. [6]
  CHEN W, LI F, OOI P C, YE Y, KIM T W, GUO T. Sens. Actuators, B, 2016, 222:763-768.
7. [7]
  ABBASABADI M K, ZAND H R E, KHODABAKHSHI S, GHOLAMI P, RASHIDI A. Res. Chem. Intermed.,2021, 47(6):2279-2296.
8. [8]
9. [9]
10. [10]
  MENG Q N, CUI J N, TANG Y F, HAN Z H, ZHAO K, ZHANG G J, DIAO Q. Ceram. Int., 2019, 45(3):4103-4107.
11. [11]
  DIAO Q, YIN Y N, ZHANG X M, LI J, JIAO M L, CAO J, QIN Q, YANG K, ZHU G X, XU X M. Funct. Mater.Lett., 2020, 13(3):2050013.
12. [12]
  HAO M, ZENG W, LI Y Q, WANG Z C. Rare Metals, 2021, 40(6):1494-1514.
13. [13]
  HAKIMI M, SALEHI A, BOROUMAND F A. IEEE Sens. J., 2016, 16(16):6149-6154.
14. [14]
  LU J, YANG J X, WANG J, LIM A, WANG S, LOH K P. ACS Nano, 2009, 3(8):2367-2375.
15. [15]
  PENG J, GAO W, GUPTA B K, LIU Z, ROMERO-ABURTO R, GE L, SONG L, ALEMANY L B, ZHAN X, GAO G,VITHAYATHIL S A, KAIPPARETTU B A, MARTI A A, HAYASHI T, ZHU J J, AJAYAN P M. Nano Lett., 2012,12(2):844-849.
16. [16]
  PAN D, ZHANG J, LI Z, WU M. Adv. Mater., 2010, 22(6):734-738.
17. [17]
  WONGRAT E, NUENGNIT T, PANYATHIP R, CHANLEK N, HONGSITH N, CHOOPUN S. Sens. Actuators, B,2021, 326:128983.
18. [18]
  HUANG H, YANG S, LI Q, YANG Y, WANG G, YOU X, MAO B, WANG H, MA Y, HE P, LIU Z, DING G, XIE X.Langmuir, 2018, 34(1):250-258.
19. [19]
  SU J, ZHANG X, TONG X, WANG X, YANG P, YAO F, GUO R, YUAN C. Mater. Lett., 2020, 271:127806.
20. [20]
  LU J, YEO P S, GAN C K, WU P, LOH K P. Nat. Nanotechnol., 2011, 6(4):247-252.
21. [21]
  KACIULIS S, MEZZI A, SOLTANI P, PIZZOFERRATO R, CIOTTA E, PROSPOSITO P. Thin Solid Films, 2019,673:19-25.
22. [22]
  HOANG T T, PHAM H P, TRAN Q T. J. Nanomater., 2020, 2020:1-8.
23. [23]
  TANG L, JI R, LI X, TENG K S, LAU S P. Part. Part. Syst. Char., 2013, 30(6):523-531.
24. [24]
  SHEHAB M, EBRAHIM S, SOLIMAN M. J. Lumin., 2017, 184:110-116.
25. [25]
  DONG Y Q, SHAO J W, CHEN C Q, LI H, WANG R X, CHI Y W, LIN X M, CHEN G N. Carbon, 2012, 50(12):4738-4743.
26. [26]
  WANG Z, YU J, ZHANG X, LI N, LIU B, LI Y, WANG Y, WANG W, LI Y, ZHANG L, DISSANAYAKE S, SUIB S L, SUN L. ACS Appl. Mater. Interfaces, 2016, 8(2):1434-1439.
27. [27]
  LIN Q, CHEN H, CAO J, ZHANG J. ACS Omega, 2021, 6(38):24940-24948.
28. [28]
  ABBAS A, TABISH T A, BULL S J, LIM T M, PHAN A N. Sci. Rep., 2020, 10:21262.
29. [29]
  YEH T F, HUANG W L, CHUNG C J, CHIANG I T, CHEN L C, CHANG H Y, SU W C, CHENG C, CHEN S J,TENG H. J. Phys. Chem. Lett., 2016, 7(11):2087-2092.
30. [30]
  YE R, PENG Z, METZGER A, LIN J, MANN J A, HUANG K, XIANG C, FAN X, SAMUEL E L G, ALEMANY L B, MART A A, TOUR J M. ACS Appl. Mater. Interfaces, 2015, 7(12):7041-7048.
31. [31]
  KWON W, KIM Y H, LEE C L, LEE M, CHOI H C, LEE T W, RHEE S W. Nano Lett., 2014, 14(3):1306-1311.
32. [32]
33. [33]
  MENG F L, SHI X, YUAN Z Y, JI H Y, QIN W B, SHEN Y B, XING C Y. Sens. Actuators, B, 2022, 350:130867.
34. [34]
  LV Y K, LI Y Y, YAO H C, LI Z J. Sens. Actuators, B, 2021, 339:129882.
35. [35]
  HAKIMI M, SALEHI A, BOROUMAND F A, MOSLEH N. IEEE Sens. J., 2018, 18(6):2245-2252.
36. [36]
  PARVIZI R, AZAD S, DASHTIAN K, GHAEDI M, HEIDARI H. Sci. Rep., 2019, 9:3798.
37. [37]
  RAHIMI K, YAZDANI A. Mater. Lett., 2018, 228(OCT.1):65-67.
38. [38]
  ZHANG Y M, ZHAO J H, SUN H L, ZHU Z Q, ZHANG J, LIU Q J. Sens. Actuators, B, 2018, 266:364-374.
39. [39]
  LIU W, ZHOU X, XU L, ZHU S, YANG S, CHEN X, DONG B, BAI X, LU G, SONG H. Nanoscale, 2019, 11(24):11496-11504.
40. [40]
  ARUNRAGSA S, SEEKAEW Y, PON-ON W, WONGCHOOSUK C. Diamond Relat. Mater., 2020, 105:107790.
41. [41]
  BAI H, SHI G. Sensors, 2007, 7(3):267-307.
42. [42]
  GAVGANI J N, HASANI A, NOURI M, MAHYARI M, SALEHI A. Sens. Actuators, B, 2016, 229:239-248.
43. [43]
  LV Y K, LI Y Y, ZHOU R H, PAN Y P, YAO H C, LI Z J. ACS Appl. Mater. Interfaces, 2020, 12(30):34245-34253.
44. [44]
  ZHANG Y H, WANG C N, YUE L J, CHEN J L, GONG F L, FANG S M. Phys. E(Amsterdam, Neth.), 2021, 133:114807.
45. [45]
  CHEN Z, WANG D, WANG X, YANG J. Chin. Chem. Lett., 2020, 31(8):2063-2066.
46. [46]
  SHAO S F, KIM H W, KIM S S, CHEN Y Y, LAI M. Appl. Surf. Sci., 2020, 516:145932.
47. [47]
  CHU X F, DAI P, DONG Y P, SUN W Q, BAI L S, ZHANG W B. J. Mater. Sci.:Mater. Electron., 2017, 28(24):19164-19173.
48. [48]
  RAEYANI D, SHOJAEI S, AHMADI-KANDJANI S. Superlattices Microstruct., 2018, 114:321-330.
49. [49]
  RAEYANI D, SHOJAEI S, AHMADI-KANDJANI S. Mater. Res. Express, 2020, 7(1):015608.
1. [1]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
2. [2]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
3. [3]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
4. [4]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
5. [5]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
6. [6]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
7. [7]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
8. [8]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
9. [9]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
13. [13]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
14. [14]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
15. [15]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
16. [16]
  Yu SU , Xinlian FAN , Yao YIN , Lin WANG . From synthesis to application: Development and prospects of InP quantum dots. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2105-2123. doi: 10.11862/CJIC.20240126
17. [17]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
18. [18]
  Xueli Mu , Lingli Han , Tao Liu . Quantum Chemical Calculation Study on the E2 Elimination Reaction of Halohydrocarbon: Designing a Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 68-75. doi: 10.12461/PKU.DXHX202404057
19. [19]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(573)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142