Citation: WEI Le, JIN Gao-Wa, DING Jun-Jie, GUO Zhi-Mou. Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(9): 1407-1414. doi: 10.19756/j.issn.0253-3820.210721 shu

Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum

WEI Le ¹ ,
JIN Gao-Wa ^2,3,, ,
DING Jun-Jie ³ ,
GUO Zhi-Mou ^2,3

1.
Conservation Department, the Palace Museum, Beijing 100009, China;
2.
CAS Key Lab of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
3.
Ganjiang Chinese Medicine Innovation Center, Nanchang 330000, China

Corresponding author: JIN Gao-Wa, jingw@dicp.ac.cn
Received Date: 2 September 2021
Revised Date: 20 June 2022

Fund Project: Supported by the National Key R&D Program of China (No.2019YFC1520300) and the National Natural Science Foundation of China (No.22074141).

The gilt brass nail components embedded in the Buddhist pagoda were coated with a special layer of dark red material which was discovered during the protection and restoration process. After pre-treatments with methanol/acid extraction, liquid chromatography-mass spectrometry (LC-MS) in combination with energy dispersive X-ray fluorescence (EDXRF), X-ray powder diffraction (XRD) and micro-Fourier transform infrared (micro-FTIR) was applied to analysis of the composition and manufacturing process. The results showed that the black layer consisted of gypsum, quartz and calcite, as well as atacamite, nantokite and weddellite as corrosion products with plant gum as effect additive. Red sandalwood was applied as coloring matter for dyeing to echo the whole style of pagoda naturally. This study provided a new view for the analysis of mix-media cultural relics.
- Gilt brass nail,
- Liquid chromatography-mass spectrometry,
- Red sandalwood,
- Cultural relics
1. [1]
  PIROK B W J, DEN UIJL M J, MORO G, BERBERS S V J, CROES C J M, VAN BOMMEL M R, SCHOENMAKERS P J. Anal. Chem., 2019, 91(4):3062-3069.
2. [2]
  HAN J, WANROOIJ J, VAN BOMMEL M, QUYE A. J. Chromatogr. A, 2017, 1479:87-96.
3. [3]
4. [4]
  TAMBURINI D, CARTWRIGHT C R, PULLAN M, VICKERS H. Archaeol. Anthrop. Sci., 2019, 11(4):1221-1239.
5. [5]
  LIU J, JI L, CHEN L, PEI K, ZHAO P, ZHOU Y, ZHAO F. Dyes Pigm., 2018, 153:137-143.
6. [6]
  CALA E, BENZI M, GOSETTI F, ZANIN A, GULMINI M, IDONE A, SERAFINI I, CICCOLA A, CURINI R, WHITWORTH I, ACETO M. Microchem. J., 2019, 150:104140.
7. [7]
  PETROVICIU I, BERGHE I V, CRETU I, ALBU F, MEDVEDOVICI A. J. Cul. Heri., 2012, 13(1):89-97.
8. [8]
  AHMED H E, TAHOUN I F, ELKHOLY I, SHEHATA A B, ZIDDAN Y. Dyes Pigm., 2017, 145:486-492.
9. [9]
  LIU J, GUO D, ZHOU Y, WU Z, LI W, ZHAO F, ZHENG X. J. Archaeol. Sci., 2011, 38(7):1763-1770.
10. [10]
  LIU J, MOURI C, LAURSEN R, ZHAO F, ZHOU Y, LI W. J. Archaeol. Sci., 2013, 40(12):4444-4449.
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
  KHORSHA S, ALIZADEH M, MASHAYEKHI K. Adv. Hort. Sci., 2016, 30(2):111-118.
24. [24]
  Philadelphia Museum of Art, Philadelphia. "IWX00086, Beeswax." Infrared and Raman Users Group, 2007. Web. .
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