Citation: SHANG Xu-Dong, WANG Chang, YU Jing-Yuan, ZHANG Yu, DU Yan. Colorimetric Detection of Fluoride Ion by Oxidase Mimics Based on Ceric Dioxide Nanorods-Polyvinyl Alcohol Aerogel[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(12): 2023-2031. doi: 10.19756/j.issn.0253-3820.210692 shu

Colorimetric Detection of Fluoride Ion by Oxidase Mimics Based on Ceric Dioxide Nanorods-Polyvinyl Alcohol Aerogel

SHANG Xu-Dong ^1,2 ,
WANG Chang ^1,3 ,
YU Jing-Yuan ^1,3 ,
ZHANG Yu ^1,3,, ,
DU Yan ^1,2,3,,

1.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
University of Chinese Academy of Sciences, Beijing 100039, China;
3.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHANG Yu, DU Yan,
Received Date: 19 August 2021
Revised Date: 25 September 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21874129) and the Department of Science and Technology of Jilin Province, China (No.20200801044GH).

This work demonstrated an oxidase mimic, e.g. a composite consisting of poly(vinyl alcohol) aerogel (PAA) and CeO₂ nanorods in-situ modified on the aerogel surface through a hydrothermal reaction. The introduction of PAA fixed the CeO₂ nanorods, making its easy to separate with reaction solution in results of an improved recycling rate. The oxidase-like activity of the composite (CeO₂-PAAC) could be elevated by fluorid ion (F^-), which was utilized to construct a colorimetric sensor for F^-, exhibiting a detection range of 80-4000 μmol/L and a detection limit (3σ) of 63.7 μmol/L. Such a value was below the Chinese criterion for the Class V surface water (80 μmol/L). Compared to other detection methods, this method had the merits of wider detection range and proportionate detection limit. Additionally, this method possessed eligible anti-interference ability and selectivity, and was adequate in detection of F^- in lake water with recovery rate of 97.1%-120.4%, validating the potential application in the real scene.
- Ceric dioxide nanorods,
- Polyvinyl alcohol aerogel,
- Colorimetry,
- Fluoride ion,
- Detection
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