Citation: LI Zhi-Xin, CHEN Shu-Ting, LUO Fang, LIN Zhen-Yu. Construction and Application of Portable Hydrogen Sulfide Sensor with Capillary Liquid Column Height as Readout[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(11): 1733-1742. doi: 10.19756/j.issn.0253-3820.210629 shu

Construction and Application of Portable Hydrogen Sulfide Sensor with Capillary Liquid Column Height as Readout

1.
Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou 350116, China;
2.
College of Biological Science and Engineering, Fuzhou University, Fuzhou 350116, China

Corresponding author: LIN Zhen-Yu, zylin@fzu.edu.cn
Received Date: 14 July 2021
Revised Date: 15 August 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21775026).

A portable sensor using the height of the liquid column in capillary as readout was designed for detection of hydrogen sulfide (H₂S). Cuprous ion (Cu⁺) could induce the combination of azide-modified magnetic beads (MBs-N₃) and alkyne-modified platinum nanoparticles (Pt NPs-Alk) through click chemistry to form platinum nanoparticles connected to magnetic beads (MBs-Pt NPs). MBs-Pt NPs could be separated from the reaction mixture by magnetic force and transferred to a glass bottle filled with hydrogen peroxide (H₂O₂) solution with a capillary on bottle cap. In the above-mentioned closed reaction device, H₂O₂ was catalytically decomposed by Pt NPs and generated a large amount of oxygen, which caused the liquid column in the capillary to rise. In the presence of H₂S, the azide groups on the surface of MBs-N₃ could be reduced to amino groups by H₂S, thereby reducing the click chemistry reaction sites between it and Pt NPs-Alk, ultimately leading to a reduction in the catalytic efficiency of H₂O₂ decomposition and a reduction in the rising height of the capillary liquid column. The change of height of the liquid column in the capillary had a linear relationship with H₂S concentration in the range of 2.0 to 60 μmol/L, and the limit of detection was 1.9 μmol/L. The method was used for the rapid and simple determination of H₂S in red wine with satisfactory results.
- Click chemistry,
- Hydrogen sulfide,
- Capillary,
- Liquid column height,
- Portable sensor
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