Citation: HUA Yun-Chen, NI Zhang, GUO Xiang-Yu, CHEN Meng, BAI Hua, MA Xiao-Xiao, LI Xiao-Xu, MA Qiang. Rapid On-Site Analysis of 12 Kinds of Hazardous Colorants in Textiles Using In-Syringe Air-Assisted Extraction Coupled with a Miniature Mass Spectrometer[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(5): 757-763. doi: 10.19756/j.issn.0253-3820.210493 shu

Rapid On-Site Analysis of 12 Kinds of Hazardous Colorants in Textiles Using In-Syringe Air-Assisted Extraction Coupled with a Miniature Mass Spectrometer

HUA Yun-Chen ^1,2 ,
NI Zhang ¹ ,
GUO Xiang-Yu ² ,
CHEN Meng ² ,
BAI Hua ² ,
MA Xiao-Xiao ³ ,
LI Xiao-Xu ^1,, ,
MA Qiang ^2,,

1.
School of Mechanical and Electric Engineering, Soochow University, Suzhou 215021, China;
2.
Chinese Academy of Inspection and Quarantine, Beijing 100176, China;
3.
State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instrument, Tsinghua University, Beijing 100084, China

Corresponding author: LI Xiao-Xu, MA Qiang,
Received Date: 10 May 2021
Revised Date: 21 February 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.21974129) and the Science Research Program of State Administration for Market Regulation of China (No.2019MK124).

A rapid, on-site protocol was developed for analysis of 12 kinds of hazardous colorants in textiles using in-syringe air-assisted extraction coupled with a self-made miniaturized linear ion trap mass spectrometer. A custom-made metal hollow needle with a tiny internal diameter enabled the aspiration of a high-speed airflow, resulting in a turbulent vortex and a highly efficient in-syringe extraction. The computational fluid dynamics of the in-syringe air-assisted extraction process was simulated. The extraction solvent, extraction cycle, and spray voltage were optimized. After extraction of target analytes, an electrospray was induced at the needle tip of the syringe, which was subjected to the detection by a miniature mass spectrometer. The limits of detection (LODs) and quantitation (LOQs) for the 12 kinds of colorants were 0.15-2.50 mg/kg and 0.40-6.00 mg/kg, respectively. The recoveries were 80.1%-106.4% with the relative standard deviations of 7.5%-15.6%. The established method was simple and efficient, and could be applied to the rapid and on-site analysis of textile samples.
- In-syringe air-assisted extraction,
- Miniature mass spectrometer,
- Rapid on-site analysis,
- Textiles,
- Colorants
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沈阳化工大学材料科学与工程学院沈阳 110142