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Citation: QI Shao-Long, DU Jian-Shi, LI Rong-Hang, LI Qiang, ZHU Lu-Bao, SHI Ya-Nan, WANG Xin-Yu, YANG Qing-Biao, ZHANG Gui-Rong, LI Yao-Xian. Synthesis of Water-soluble Fluorescent Probe for Dual Detection of HSO₃^- and pH Value[J]. Chinese Journal of Analytical Chemistry, ;2020, 48(3): 347-354. doi: 10.19756/j.issn.0253-3820.191609 shu

Synthesis of Water-soluble Fluorescent Probe for Dual Detection of HSO₃^- and pH Value

1.
China-Japan Union Hospital of Jilin University, Key Laboratory of Lymphatic Surgery Jilin Province, Engineering Laboratory of Lymphatic Surgery Jilin Province, Changchun 130031, China;
2.
College of Chemistry, Jilin University, Changchun 130061, China;
3.
School of Life Sciences, Jilin University, Changchun 130061, China;
4.
The Second Hospital of Jilin University, Changchun 130041, China

Received Date: 16 October 2019
Revised Date: 20 December 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (No.21174052), the Key Projects of Jilin Province Science and Technology Department, China (No.20180201085GX) and the Provincial Industrial Innovation Special Fund Project of Jilin Province, China (No.2018C052-5).

Three new fluorescent probes (ISBD, ISPD and ISND) were designed and synthesized. The UV-visible absorption spectrum, fluorescence spectrum, and response to pH values of the probe were studied, and the HSO₃^-/pH dual detection fluorescent probe ISND with stronger fluorescence intensity (higher fluorescence quantum yield), longer emission wavelength and less interference was selected for the further study. The probe ISND could be used for the sensitive and specific detection of HSO₃^-, with a detection limit of 8.11×10^-8 mol/L (λ_em=458 nm, response time <1 min). In addition, with different emission wavelength (λ_em=565 nm), the probe could accurately detect pH value. Furthermore, the probe ISND had many advantages such as low toxicity and good membrane permeability. It could achieve fluorescence imaging of HSO₃^- in living cell, and exhibited good application prospects in sensing, biological signal transduction and detection.
- Fluorescence probe,
- Indole sulfonate,
- pH value,
- Bisulfite
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1.
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