Citation: ZHANG Teng, ZHONG Yi-Han, ZHANG Shou-Ting, DANG Xin-Yu, LU Xiao-Quan. A Sensitive Colorimetric Method for Detection of Chromium Ion(Ⅲ) Based on Surface Plasmon Resonance Effect of Gold Nanoparticles[J]. Chinese Journal of Analytical Chemistry, ;2019, 47(9): 1373-1381. doi: 10.19756/j.issn.0253-3820.191306 shu

A Sensitive Colorimetric Method for Detection of Chromium Ion(Ⅲ) Based on Surface Plasmon Resonance Effect of Gold Nanoparticles

1.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China;
2.
Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Received Date: 25 May 2019
Revised Date: 8 July 2019

Fund Project: This coork was supported by the National Natural Science Foundation of China (Nos. 21575115, 21705117).

A method was proposed for the effective and accurate colorimetric detection of ultra-trace trivalent chromium ions (Cr³⁺) in water based on citric acid-modified gold nanoparticles (CA-AuNPs). CA-AuNPs under different pH conditions were prepared by in-situ reduction at 273 K. After adding ultra-trace Cr³⁺, the color change of the system was visible to the naked eye, and the color changed from red to dark gray or colorless, other metal ions (Na⁺, Ca²⁺, Co²⁺, Zn²⁺, Cu²⁺, Fe²⁺, Mg²⁺, Al³⁺, Fe³⁺) showed no significant changes. The proposed sensing strategy coupled with spectroscopic detection method showed a low detection limit of 40.7 nmol/L(3σ) for detection of Cr³⁺in drinking water, which was lower than that of the national standard method. And a minimum concentration of 1.0×10^-5 mol/L for Cr³⁺ could be detected with naked eyes. This visual sensor based on CA-AuNPs had low detection limit and high selectivity, which would play an important role in drug analysis, clinical diagnosis and environmental monitoring.
- Surface plasmon resonance,
- Gold nanoparticles,
- Trivalent chromium ions,
- Visualization
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