Citation: XU Jun, HUANG Ming-Qiang. Influence of Inorganic Gases on Formation and Chemical Composition of Monoaromatic Hydrocarbons Secondary Organic Aerosol[J]. Chinese Journal of Analytical Chemistry, ;2020, 48(4): 449-462. doi: 10.19756/j.issn.0253-3820.191235 shu

Influence of Inorganic Gases on Formation and Chemical Composition of Monoaromatic Hydrocarbons Secondary Organic Aerosol

XU Jun ,
HUANG Ming-Qiang

College of Chemistry & Chemical Engineering and Environment, Minnan Normal University, Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, Zhangzhou 363000, China

Received Date: 27 April 2019
Revised Date: 6 January 2020

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 41575118, 41305109), and the Science Fund for Distinguished Young Scholars of Fujian Province, China (No. 2015J06009).

SO₂, NO_x and NH₃ are low molecular weight inorganic gas and are commonly found in the atmosphere that can affect the formation and chemical composition of secondary organic aerosols (SOA) through photochemical reaction processes. Volatile organic compounds (VOCs) from motor vehicle exhaust, such as monoaromatic hydrocarbons, are an important component of urban fine particulate matter, which has a significant impact on climate change, human health and atmospheric visibility. However, previous studies focused on photooxidation of biogenic volatile organic compounds, and relatively few on the reaction of anthropogenic monoaromatic hydrocarbons with high content in the atmosphere with inorganic gases such as SO₂, NO_x and NH₃. This paper summarizes the photochemical mechanism and five kinds of common chemical composition of the laboratory simulation of OH radical to initiate monoaromatic hydrocarbons formation of SOA, and the effects of SO₂, NO_x and NH₃ on the formation and chemical composition of monoaromatic hydrocarbons SOA by homogeneous and heterogeneous chemical reactions are also discussed. It is helpful to understand the formation mechanism and chemical composition of SOA and atmospheric brown carbon under the conditions of complex atmospheric pollution, and has certain reference significance for the prevention, control and treatment of air pollution in china at present.
- Inorganic gases,
- Monoaromatic hydrocarbons,
- Secondary organic aerosol,
- Chemical composition,
- Formation mechanism,
- Review
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