Citation: HUANG Xiao-Mei, WU Yang, CUI Jun-Tao, WANG Fu-Hua, WANG Xu, LI Ya-Fei, WU Wei-Yun. Applications of High-Resolution Mass Spectrometry in Determination of Chlorinated Paraffins[J]. Chinese Journal of Analytical Chemistry, ;2019, 47(3): 323-334. doi: 10.19756/j.issn.0253-3820.181586 shu

Applications of High-Resolution Mass Spectrometry in Determination of Chlorinated Paraffins

HUANG Xiao-Mei ^1,3, ,
WU Yang ^2,4 ,
CUI Jun-Tao ^2,4 ,
WANG Fu-Hua ^1,3 ,
WANG Xu ^1,3 ,
LI Ya-Fei ^1,3 ,
WU Wei-Yun ^1,3

1.
Public Monitoring Center for Agro-product of Guangdong Academy of Agricultural Sciences, Guangzhou 510640, China;
2.
State Key Laboratory of Organic Geochemistry, Guangdong Provincial Key Laboratory of Utilization and Protection of Environmental Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;
3.
Laboratory of Quality & Safety Risk Assessment for Agro-products(Guangzhou), Ministry of Agriculture and Rural Affairs, Guangzhou 510460, China;
4.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 9 September 2018
Revised Date: 26 November 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 41807380), the Standardization Research Project of Guangdong Province, China (Guangdong Finance and Agriculture[2016] No. 310), the Special Talent Projects in Guangdong Academy of Agricultural Sciences (Guangdong Agriculture Sciences Talents[2018] No.3) and the New Discipline Team Project in Guangdong Academy of Agricultural Sciences (No. 201804XX).

Chlorinated paraffins (CPs) are a new class of persistent organic pollutants and have aroused great concern of many environmental scientists due to their ubiquity in various environmental media and biotas. Given their relative low levels in environmental samples, CPs need to be enriched and cleaned up before instrumental analysis. CPs consist of thousands of congeners and isomers, thus posing grand challenges to eliminate the mass interference by homologues and other organohalogen compounds during instrumental examination. Fortunately, high-resolution mass spectrometry (HRMS) owns the powerful ability to solve this key problem owing to its high mass resolution. This review introduced the methods of pretreatment and instrumental analysis of CPs-containing samples in the environment, mainly illustrating the application of gas chromatography and liquid chromatography coupled with HRMS (i.e. GC-HRMS and LC-HRMS). The existing issues and prospects of future study were also discussed.
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