Citation: Zhi-Qiang LU, Yan-Zhi LI, Chu HAO, Yi RU, Shu-Jian YANG, Ning-Dan ZHANG, Yu-Qin FU, Wei-Long WU, Yan ZHOU. Synthesis, Crystal Structure and Luminescent/magnetic Properties of Two Metal-organic Frameworks Based on Multi-N/O-donor Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1122-1130. doi: 10.14102/j.cnki.0254–5861.2011–3206 shu

Synthesis, Crystal Structure and Luminescent/magnetic Properties of Two Metal-organic Frameworks Based on Multi-N/O-donor Mixed Ligands

Zhi-Qiang LU ^{a, b,,} ,
Yan-Zhi LI ^{a, b} ,
Chu HAO ^b ,
Yi RU ^b ,
Shu-Jian YANG ^b ,
Ning-Dan ZHANG ^b ,
Yu-Qin FU ^b,, ,
Wei-Long WU ^b ,
Yan ZHOU ^b

a.
Hubei Key Laboratory of Natural Products Research and Development, Key Laboratory of Functional Yeast (China National Light Industry), College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, China
b.
Luoyang Key Laboratory of Organic Functional Molecules, School of Chemistry & Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Zhi-Qiang LU, zqlu2000@163.com Yu-Qin FU, lyfuyuqin@126.com
Received Date: 6 April 2021
Accepted Date: 15 June 2021

Fund Project: the National Natural Science Foundation of China U1304206the National Natural Science Foundation of China 21801112Natural Science Foundation of Henan Province 212300410374Science and Technology Project of Hennan Province 212102210549the Key Scientific Research Project of Higher Education of Henan Province 13A150799

Figures(13)

Two new complexes, namely [Cd₂(L)(pycy)(Cl)]·2H₂O (1) and [Cu(HL)(H₂btac)]·2H₂O, have been synthesized by the reaction of the corresponding metal salts with mixed ligands including 1-(1H-imidazol-4-yl)-4-(4H-tetrazol-5-yl)benzene (HL), 2, 6-pyridinedicarboxylic acid (H₂pycy) and 1, 2, 4, 5-benzenetetracarboxylic acid (H₄btac), and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and powder X-ray diffraction (PXRD). Complex 1 crystallizes in triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 9.8938(7), b = 10.1662(7), c = 12.4520(8) Å, α = 92.7070(10), β = 108.1310(10), γ = 105.3230(10)°, V = 1136.44(13) Å³, Z = 2, C₁₇H₁₂N₇O₆ClCd₂, M_r = 670.59, D_c = 1.960 g/cm³, μ = 2.037 mm^-1, S = 1.062, F(000) = 648, the final R = 0.0532 and wR = 0.1651 for 12156 observed reflections (I > 2σ(I)). Complex 2 crystallizes in triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 7.3058(8), b = 7.4890(8), c = 10.8937(12) Å, α = 71.3810(10), β = 84.134(2), γ = 65.745(2)°, V = 514.68(10) Å³, Z = 1, C₂₀H₁₆CuN₆O₁₀, M_r = 563.94, D_c = 1.819 g/cm³, μ = 1.139 mm^-1, S = 1.187, F(000) = 287, the final R = 0.0314 and wR = 0.0807 for 3564 observed reflections (I > 2σ(I)). Single-crystal X-ray structural analysis reveals that complex 1 features a trinodal (3, 3, 4)-connected two-dimensional (2D) net layer with Schläfli symbol (4·6·8)(4·6²·8³)(6²·8) while 2 has a 2D network with 4⁴ sql topology. Moreover, the photoluminescent property of 1 and magnetic property of 2 were also discussed.
- synthesis,
- complex,
- luminescence,
- magnetic property
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