Citation: Ming WANG, Xiao-Mei WANG, Ming-Yu CHEN, Cheng LIU, Ge DING, Xin-Hui ZHOU. A Water-stable Tetranuclear Cd(Ⅱ) Bicyclic Complex Used for the Picric Acid Detection[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1461-1468. doi: 10.14102/j.cnki.0254–5861.2011–3182 shu

A Water-stable Tetranuclear Cd(Ⅱ) Bicyclic Complex Used for the Picric Acid Detection

Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: Xin-Hui ZHOU, iamxhzhou@njupt.edu.cn
Received Date: 18 March 2021
Accepted Date: 8 June 2021

Fund Project: the National Natural Science Foundation of China 21973047Jiangsu Province Double Innovation Talent Program 090300014001

Figures(7)

By solvothermal reaction of Cd(Ⅱ) with organic ligand N, N΄-bis(3, 5-dicarboxylphenyl)-thiophene-2, 5-dicarboxamide (H₄L), a water-stable complex [Cd₄(H₂L)₄(H₂O)₁₀]·2CH₃OH·8H₂O·4DMF (1, C₁₀₂H₁₂₀Cd₄N₁₂O₆₄S₄) has been successfully synthetized (DMF = N, N-dimethylformamide). 1 crystallizes in the triclinic space group of P\begin{document}$ \overline 1 $\end{document} with a = 11.815(7), b = 16.209(9), c = 16.742(9) Å, α = 82.224(13)º, β = 76.741(13)º, γ = 70.313(12)º, V = 2932(3) Å³, M_r = 3115.93, Z = 1, F(000) = 1584, D_c = 1.765 Mg/cm³, µ = 0.901 mm⁻¹, GOOF = 1.101, the final R = 0.0391 and wR = 0.1297 for 9007 observed reflections (I > 2σ(I)). 1 is a tetranuclear Cd(Ⅱ) bicyclic complex with strong ligand-based blue emission and can stably exist in aqueous solutions over the pH range of 2-11. 1 exhibits high sensitivity, selectivity and anti-interference capability for picric acid (PA) detection in aqueous solution by luminescent quenching. The value of quenching constant (K_sv) is 3.2 × 10⁴ M^-1 within the PA concentration range of 0~40 μM and the detection limit is 6.89 × 10^-7 M. Lastly, we went into depth on possible mechanism of the luminescent quenching.
- sensors,
- complex,
- picric acid,
- fluorescence
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