Citation: Yu-Lin WU, Ning XIE, Xiao-Fang LI, Zhao-Ming FU, Xin-Tao WU, Qi-Long ZHU. MOF-derived Hierarchical Hollow NiRu-C Nanohybrid for Efficient Hydrogen Evolution Reaction[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1346-1356. doi: 10.14102/j.cnki.0254–5861.2011–3153 shu

MOF-derived Hierarchical Hollow NiRu-C Nanohybrid for Efficient Hydrogen Evolution Reaction

Yu-Lin WU ^{a, b} ,
Ning XIE ^{a, b} ,
Xiao-Fang LI ^b,, ,
Zhao-Ming FU ^e,, ,
Xin-Tao WU ^{b, c, d} ,
Qi-Long ZHU ^{b, c, d,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
d.
University of Chinese Academy of Sciences, Beijing 100049, China
e.
Physics and Electronic Information College, Yunnan Normal University, Kunming 650500, China

Corresponding author: Xiao-Fang LI, lixiaofang@fjirsm.ac.cn Zhao-Ming FU, fuzhm1979@163.com Qi-Long ZHU, qlzhu@fjirsm.ac.cn
Received Date: 2 February 2021
Accepted Date: 31 March 2021

Fund Project: the National Natural Science Foundation of China (NSFC) 21901246the National Natural Science Foundation of China (NSFC) 21905279the Natural Science Foundation of Fujian Province 2020J01116the Natural Science Foundation of Fujian Province 2019J05158

Figures(11)

Designing efficient electrocatalysts for efficient hydrogen evolution is extremely desired but challenging. Herein, we report a facile MOF-assisted strategy to synthesize the hierarchical hollow spherical NiRu-C nanohybrid with closely packed rod-like bulges on the surface. Benefited from the more exposed active sites of NiRu-C nanohybrid and the efficient electron/mass transport in its unique hierarchical hollow spherical nanostructure, the optimized nanohybrid showed excellent performance for alkaline hydrogen evolution with ultralow overpotentials, which are much superior to those of Pt/C and the overwhelming majority of reported electrocatalysts. The interpretation of the reaction mechanism was further discussed with DFT calculations. Our research may provide a guidance for the development of advanced electrocatalysts with controlled morphology and excellent performance for future energy applications.
- hydrogen evolution reaction,
- NiRu,
- hollow spherical nanostructure,
- electrocatalysis
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