Citation: Deng-Peng LI, Zhi-Huang XU, Li-Wang YE, Teng-Fei CAO, Xin-Xin ZHUANG. Synthesis, Structure and Characterization of a New Complex: [Mn(C₆H₁₂N₄)₂(H₂O)₄][Mn(H₂O)₆][SO₄]₂·6H₂O[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1169-1176. doi: 10.14102/j.cnki.0254–5861.2011–3119 shu

Synthesis, Structure and Characterization of a New Complex: [Mn(C₆H₁₂N₄)₂(H₂O)₄][Mn(H₂O)₆][SO₄]₂·6H₂O

Deng-Peng LI ^{a, b} ,
Zhi-Huang XU ^b ,
Li-Wang YE ^b ,
Teng-Fei CAO ^{a, b} ,
Xin-Xin ZHUANG ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Xin-Xin ZHUANG, zxx@fjirsm.ac.cn
Received Date: 25 January 2021
Accepted Date: 15 March 2021

Figures(6)

A novel complex, [Mn(C₆H₁₂N₄)₂(H₂O)₄][Mn(H₂O)₆][SO₄]₂·6H₂O, was synthesized and hexagonal single crystals with centimeter-scale sizes were obtained by the method of solvent evaporation. It was characterized by elemental analysis, infrared spectrum, thermogravimetric analysis and X-ray single-crystal diffraction. The complex belongs to triclinic crystal system, space group P\begin{document}$ \overline 1 $\end{document} with a = 9.3390(8), b = 13.3520(13), c = 16.3207(13) Å, α = 100.7160(3)°, β = 90.1020(10)°, γ = 109.9490(5)°, V = 1874.9(3) Å³, Z = 2, D_c = 1.542 g/cm³, M_r = 870.64, μ = 0.876 mm^-1, T = 293(2) K, F(000) = 916 and S = 0.990. The crystal structure determination displayed a distorted octahedral geometry around the manganese atom, which is bound to two nitrogen atoms from hexamethylenetetramine, acting as monodentate ligands, and to four aqua ligands. Variable-temperature magnetic measurements of the complex indicate the presence of weak antiferromagnetic interaction between manganese centers.
- hexamethylenetetramine,
- crystal structure,
- thermal stability,
- susceptibility
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Synthesis, Structure and Characterization of a New Complex: [Mn(C6H12N4)2(H2O)4][Mn(H2O)6][SO4]2·6H2O

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Synthesis, Structure and Characterization of a New Complex: [Mn(C₆H₁₂N₄)₂(H₂O)₄][Mn(H₂O)₆][SO₄]₂·6H₂O