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Citation: Meng-Di ZHANG, Jun-Dong YI, Yuan-Biao HUANG, Rong CAO. Covalent Triazine Frameworks-derived N, P Dual-doped Porous Carbons for Highly Efficient Electrochemical Reduction of CO2[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1213-1222. doi: 10.14102/j.cnki.0254–5861.2011–3118 shu

Covalent Triazine Frameworks-derived N, P Dual-doped Porous Carbons for Highly Efficient Electrochemical Reduction of CO2

  • a.

    College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

  • b.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • c.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • d.

    Fujian College, University of Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Yuan-Biao HUANG, ybhuang@fjirsm.ac.cn Rong CAO, rcao@fjirsm.ac.cn
  • Received Date: 5 January 2021
    Accepted Date: 3 March 2021

    Fund Project: the National Key Research and Development Program of China 2018YFA0208600the National Key Research and Development Program of China 2018YFA0704502NSFC 21871263NSFC 22071245NSFC 22033008Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the Youth Innovation Promotion Association, CAS Y201850

Figures(6)

  • Electroreduction of CO2 into chemicals is of great importance in the global carbon balance. Although noble-metal based catalysts and single-atom catalysts (SACs) are known to be active for CO2 electroreduction reaction (CO2RR), the high cost of noble-metal and the lack of effective synthesis approaches to prepare SACs have tremendously hindered the application. Non-metal doped carbon materials have attracted great interest because of their reasonable cost, chemical stability and excellent electrical conductivity. Nevertheless, the design and fabrication of highly efficient non-metal doped carbon electrocatalysts for CO2RR to meet industry demands still remains a big challenge. Herein, triphenylphosphine@covalent triazine framework (CTF) composites were employed as precursors to fabricate N, P dual-doped porous carbon catalysts PCTF-X-Y (X represents the carbonization temperature, and Y represents the mass ratio of CTF to triphenylphosphine) for CO2RR. Due to the high specific surface areas and synergistic effect between N and P, the obtained PCTF-1000-5 exhibited high selectivity for CO production up to 84.3% at –0.7 V versus the reversible hydrogen electrode (vs. RHE) and long-term durability over 16 h, which are better than the reported N, P dual-doped carbon catalysts in aqueous media. This work provides a new way to design and fabricate non-metal catalysts for electrocatalysis.
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