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Citation: Meng-Di ZHANG, Jun-Dong YI, Yuan-Biao HUANG, Rong CAO. Covalent Triazine Frameworks-derived N, P Dual-doped Porous Carbons for Highly Efficient Electrochemical Reduction of CO2[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1213-1222. doi: 10.14102/j.cnki.0254–5861.2011–3118 shu

Covalent Triazine Frameworks-derived N, P Dual-doped Porous Carbons for Highly Efficient Electrochemical Reduction of CO2

  • a.

    College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

  • b.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • c.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • d.

    Fujian College, University of Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Yuan-Biao HUANG, ybhuang@fjirsm.ac.cn Rong CAO, rcao@fjirsm.ac.cn
  • Received Date: 5 January 2021
    Accepted Date: 3 March 2021

    Fund Project: the National Key Research and Development Program of China 2018YFA0208600the National Key Research and Development Program of China 2018YFA0704502NSFC 21871263NSFC 22071245NSFC 22033008Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the Youth Innovation Promotion Association, CAS Y201850

Figures(6)

  • Electroreduction of CO2 into chemicals is of great importance in the global carbon balance. Although noble-metal based catalysts and single-atom catalysts (SACs) are known to be active for CO2 electroreduction reaction (CO2RR), the high cost of noble-metal and the lack of effective synthesis approaches to prepare SACs have tremendously hindered the application. Non-metal doped carbon materials have attracted great interest because of their reasonable cost, chemical stability and excellent electrical conductivity. Nevertheless, the design and fabrication of highly efficient non-metal doped carbon electrocatalysts for CO2RR to meet industry demands still remains a big challenge. Herein, triphenylphosphine@covalent triazine framework (CTF) composites were employed as precursors to fabricate N, P dual-doped porous carbon catalysts PCTF-X-Y (X represents the carbonization temperature, and Y represents the mass ratio of CTF to triphenylphosphine) for CO2RR. Due to the high specific surface areas and synergistic effect between N and P, the obtained PCTF-1000-5 exhibited high selectivity for CO production up to 84.3% at –0.7 V versus the reversible hydrogen electrode (vs. RHE) and long-term durability over 16 h, which are better than the reported N, P dual-doped carbon catalysts in aqueous media. This work provides a new way to design and fabricate non-metal catalysts for electrocatalysis.
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    1. [1]

      Duan, X.; Xu, J.; Wei, Z.; Ma, J.; Guo, S.; Wang, S.; Liu, H.; Dou, S. Metal-free carbon materials for CO2 electrochemical reduction. Adv. Mater. 2017, 29, 1701784.  doi: 10.1002/adma.201701784

    2. [2]

      Yi, J. D.; Xie, R.; Xie, Z. L.; Chai, G. L.; Liu, T. F.; Chen, R. P.; Huang, Y. B.; Cao, R. Highly selective CO2 electroreduction to CH4 by in situ generated Cu2O single-type sites on a conductive MOF: stabilizing key intermediates with hydrogen bonding. Angew. Chem. Int. Ed. 2020, 59, 23641–23648.  doi: 10.1002/anie.202010601

    3. [3]

      Wu, Q.; Mao, M. J.; Wu, Q. J.; Liang, J.; Huang, Y. B.; Cao, R. Construction of donor-acceptor heterojunctions in covalent organic framework for enhanced CO2 electroreduction. Small 2020, 2004933.

    4. [4]

      Zhu, H. J.; Lu, M.; Wang, Y. R.; Yao, S. J.; Zhang, M.; Kan, Y. H.; Liu, J.; Chen, Y.; Li, S. L.; Lan, Y. Q. Efficient electron transmission in covalent organic framework nanosheets for highly active electrocatalytic carbon dioxide reduction. Nat. Commun. 2020, 11, 497.  doi: 10.1038/s41467-019-14237-4

    5. [5]

      Ye, K.; Wang, G. X.; Bao, X. H. Electrodeposited Sn-based catalysts for CO2 electroreduction. Chin. J. Struct. Chem. 2020, 39, 206‒213.

    6. [6]

      Lu, M.; Zhang, M.; Liu, C. G.; Liu, J.; Shang, L. J.; Wang, M.; Chang, J. N.; Li, S. L.; Lan, Y. Q. Stable dioxin-linked metallophthalocyanine covalent organic frameworks (COFs) as photo-coupled electrocatalysts for CO2 reduction. Angew. Chem. Int. Ed. 2021, DOI: 10.1002/anie.202011722.

    7. [7]

      Huang, Q.; Li, Q.; Liu, J.; Wang, Y. R.; Wang, R.; Dong, L. Z.; Xia, Y. H.; Wang, J. L.; Lan, Y. Q. Disclosing CO2 activation mechanism by hydroxyl-induced crystalline structure transformation in electrocatalytic process. Matter 2019, 1, 1656‒1668.  doi: 10.1016/j.matt.2019.07.003

    8. [8]

      Hou, S. S.; Xu, Z. T.; Zhang, Y. K.; Xie, K.; Gan, L. Z. Enhanced CO2 electrolysis with Mn-doped SrFeO3-delta cathode. Chin. J. Struct. Chem. 2020, 39, 1662‒1668.

    9. [9]

      Xu, Z. T.; Xie, K. Enhanced CO2 electrolysis with metal-oxide interface structures. Chin. J. Struct. Chem. 2021, 40, 31‒41.

    10. [10]

      Nielsen, D. U.; Hu, X. M.; Daasbjerg, K.; Skrydstrup, T. Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals. Nat. Catal. 2018, 1, 244‒254.  doi: 10.1038/s41929-018-0051-3

    11. [11]

      Sheng, W. C.; Kattel, S.; Yao, S. Y.; Yan, B. H.; Liang, Z. X.; Hawxhurst, C. J.; Wu, Q. Y.; Chen, J. G. G. Electrochemical reduction of CO2 to synthesis gas with controlled CO/H2 ratios. Energy Environ. Sci. 2017, 10, 1180‒1185.  doi: 10.1039/C7EE00071E

    12. [12]

      Wu, J. J.; Yadav, R. M.; Liu, M. J.; Sharma, P. P.; Tiwary, C. S.; Ma, L. L.; Zou, X. L.; Zhou, X. D.; Yakobson, B. I.; Lou, J.; Ajayan, P. M. Achieving highly efficient, selective, and stable CO2 reduction on nitrogen-doped carbon nanotubes. Acs Nano 2015, 9, 5364‒5371.  doi: 10.1021/acsnano.5b01079

    13. [13]

      Long, C.; Li, X.; Guo, J.; Shi, Y. N.; Liu, S. Q.; Tang, Z. Y. Electrochemical reduction of CO2 over heterogeneous catalysts in aqueous solution: recent progress and perspectives. Small Methods 2019, 3, 1800369.

    14. [14]

      Zhang, M. D.; Si, D. H.; Yi, J. D.; Zhao, S. S.; Huang, Y. B.; Cao, R. Conductive phthalocyanine-based covalent organic framework for highly efficient electroreduction of carbon dioxide. Small 2020, 16, 2005254.  doi: 10.1002/smll.202005254

    15. [15]

      Mezzavilla, S.; Horch, S.; Stephens, I. E. L.; Seger, B.; Chorkendorff, I. Structure sensitivity in the electrocatalytic reduction of CO2 with gold catalysts. Angew. Chem. Int. Ed. 2019, 58, 3774‒3778.  doi: 10.1002/anie.201811422

    16. [16]

      Li, Y. F.; Chen, C.; Cao, R.; Pan, Z. W.; He, H.; Zhou, K. B. Dual-atom Ag2/graphene catalyst for efficient electroreduction of CO2 to CO. Appl. Catal. B-Environ. 2020, 268, 118747.  doi: 10.1016/j.apcatb.2020.118747

    17. [17]

      Gao, D. F.; Zhou, H.; Cai, F.; Wang, J. G.; Wang, G. X.; Bao, X. H. Pd-containing nanostructures for electrochemical CO2 reduction reaction. ACS Catal. 2018, 8, 1510‒1519.  doi: 10.1021/acscatal.7b03612

    18. [18]

      Wang, A.; Li, J.; Zhang, T. Heterogeneous single-atom catalysis. Nat. Rev. Chem. 2018, 2, 65‒81.  doi: 10.1038/s41570-018-0010-1

    19. [19]

      Yang, H. B.; Hung, S. F.; Liu, S.; Yuan, K. D.; Miao, S.; Zhang, L. P.; Huang, X.; Wang, H. Y.; Cai, W. Z.; Chen, R.; Gao, J. J.; Yang, X. F.; Chen, W.; Huang, Y. Q.; Chen, H. M.; Li, C. M.; Zhang, T.; Liu, B. Atomically dispersed Ni(Ι) as the active site for electrochemical CO2 reduction. Nat. Energy 2018, 3, 140‒147.  doi: 10.1038/s41560-017-0078-8

    20. [20]

      Hou, Y.; Chai, G. L.; Liang, Y. L.; Yi, J. D.; Zhang, T.; Zang, K. T.; Luo, J.; Xu, R.; Lin, H.; Zhang, S. Y.; Wang, H. M.; Huang, Y. B.; Cao, R. Unraveling the reactivity and selectivity of atomically isolated metal-nitrogen sites anchored on porphyrinic triazine frameworks for electroreduction of CO2. CCS Chem. 2019, 1, 384‒395.  doi: 10.31635/ccschem.019.20190011

    21. [21]

      Zheng, T. T.; Jiang, K.; Ta, N.; Hu, Y. F.; Zeng, J.; Liu, J. Y.; Wang, H. T. Large-scale and highly selective CO2 electrocatalytic reduction on nickel single-atom catalyst. Joule 2019, 3, 265‒278.  doi: 10.1016/j.joule.2018.10.015

    22. [22]

      Zhao, C.; Dai, X.; Yao, T.; Chen, W.; Wang, X.; Wang, J.; Yang, J.; Wei, S.; Wu, Y.; Li, Y. Ionic exchange of metal organic frameworks to access single nickel sites for efficient electroreduction of CO2. J. Am. Chem. Soc. 2017, 139, 8078‒8081.  doi: 10.1021/jacs.7b02736

    23. [23]

      Jiao, L.; Yang, W.; Wan, G.; Zhang, R.; Zheng, X.; Zhou, H.; Yu, S. H.; Jiang, H. L. Single-atom electrocatalysts from multivariate metal-organic frameworks for highly selective reduction of CO2 at low pressures. Angew. Chem. Int. Ed. 2020, 59, 20589‒20595.  doi: 10.1002/anie.202008787

    24. [24]

      Zhang, W. J.; Hu, Y.; Ma, L. B.; Zhu, G. Y.; Wang, Y. R.; Xue, X. L.; Chen, R. P.; Yang, S. Y.; Jin, Z. Progress and perspective of electrocatalytic CO2 reduction for renewable carbonaceous fuels and chemicals. Adv. Sci. 2018, 5, 1700275.  doi: 10.1002/advs.201700275

    25. [25]

      Zhang, Q. Q.; Guan, J. Q. Single-atom catalysts for electrocatalytic applications. Adv. Funct. Mater. 2020, 30, 2000768.  doi: 10.1002/adfm.202000768

    26. [26]

      Pan, Y.; Qian, Y.; Zheng, X.; Chu, S. Q.; Yang, Y.; Ding, C.; Wang, X.; Yu, S. H.; Jiang, H. L. Precise fabrication of single-atom alloy co-catalyst with optimal charge state for enhanced photocatalysis. Natl. Sci. Rev. 2021, 8, nwaa224.  doi: 10.1093/nsr/nwaa224

    27. [27]

      Jiao, L.; Zhang, R.; Wan, G.; Yang, W.; Wan, X.; Zhou, H.; Shui, J.; Yu, S. H.; Jiang, H. L. Nanocasting SiO2 into metal-organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts. Nat. Commun. 2020, 11, 2831.  doi: 10.1038/s41467-020-16715-6

    28. [28]

      Benzigar, M. R.; Talapaneni, S. N.; Joseph, S.; Ramadass, K.; Singh, G.; Scaranto, J.; Ravon, U.; Al-Bahily, K.; Vinu, A. Recent advances in functionalized micro and mesoporous carbon materials: synthesis and applications. Chem. Soc. Rev. 2018, 47, 2680‒2721.  doi: 10.1039/C7CS00787F

    29. [29]

      Paul, R.; Zhu, L.; Chen, H.; Qu, J.; Dai, L. M. Recent advances in carbon-based metal-free electrocatalysts. Adv. Mater. 2019, 31, 1806403.  doi: 10.1002/adma.201806403

    30. [30]

      Liu, X.; Dai, L. M. Carbon-based metal-free catalysts. Nat. Rev. Mater. 2016, 1, 16064.  doi: 10.1038/natrevmats.2016.64

    31. [31]

      You, S. J.; Ma, M.; Wang, W.; Qi, D. P.; Chen, X. D.; Qu, J. H.; Ren, N. Q. 3D Macroporous nitrogen-enriched graphitic carbon scaffold for efficient bioelectricity generation in microbial fuel Cells. Adv. Energy Mater. 2017, 7, 1601364.  doi: 10.1002/aenm.201601364

    32. [32]

      Sharma, P. P.; Wu, J.; Yadav, R. M.; Liu, M.; Wright, C. J.; Tiwary, C. S.; Yakobson, B. I.; Lou, J.; Ajayan, P. M.; Zhou, X. D. Nitrogen-doped carbon nanotube arrays for high-efficiency electrochemical reduction of CO2: on the understanding of defects, defect density, and selectivity. Angew. Chem. Int. Ed. 2015, 54, 13701‒13705.  doi: 10.1002/anie.201506062

    33. [33]

      Liu, T.; Ali, S.; Lian, Z.; Si, C.; Su, D. S.; Li, B. Phosphorus-doped onion-like carbon for CO2 electrochemical reduction: the decisive role of the bonding configuration of phosphorus. J. Mater. Chem. A 2018, 6, 19998‒20004.  doi: 10.1039/C8TA06649C

    34. [34]

      Xie, J.; Zhao, X.; Wu, M.; Li, Q.; Wang, Y.; Yao, J. Metal-free fluorine-doped carbon electrocatalyst for CO2 reduction outcompeting hydrogen evolution. Angew. Chem. Int. Ed. 2018, 57, 9640‒9644.  doi: 10.1002/anie.201802055

    35. [35]

      Hu, C. G.; Dai, L. M. Doping of carbon materials formetal-free electrocatalysis. Adv. Mater. 2019, 31, 1804672.  doi: 10.1002/adma.201804672

    36. [36]

      Yang, W. G.; Gong, Z. W.; Chen, Y. N.; Chen, R. R.; Meng, D. L.; Cao, M. N. Nitrogen doped carbon as efficient catalyst toward oxygen reduction reaction. Chin. J. Struct. Chem. 2020, 39, 287‒293.

    37. [37]

      Cui, X.; Pan, Z.; Zhang, L.; Peng, H.; Zheng, G. Selective etching of nitrogen-doped carbon by steam for enhanced electrochemical CO2 reduction. Adv. Energy Mater. 2017, 7, 1701456.  doi: 10.1002/aenm.201701456

    38. [38]

      Chen, Y. Z.; Wang, C.; Wu, Z. Y.; Xiong, Y.; Xu, Q.; Yu, S. H.; Jiang, H. L. From bimetallic metal-organic framework to porous carbon: high surface area and multicomponent active dopants for excellent electrocatalysis. Adv. Mater. 2015, 27, 5010‒5016.  doi: 10.1002/adma.201502315

    39. [39]

      Zhu, L. W.; Wu, J.; Zhang, Q.; Li, X. K.; Li, Y. M.; Cao, X. B. Chemical-free fabrication of N, P dual-doped honeycomb-like carbon as an efficient electrocatalyst for oxygen reduction. J. Colloid Interface Sci. 2018, 510, 32‒38.  doi: 10.1016/j.jcis.2017.08.078

    40. [40]

      Xue, X.; Yang, H.; Yang, T.; Yuan, P.; Li, Q.; Mu, S.; Zheng, X.; Chi, L.; Zhu, J.; Li, Y.; Zhang, J.; Xu, Q. N, P-coordinated fullerene-like carbon nanostructures with dual active centers toward high-efficient multi-functional electrocatalysis for CO2RR, ORR and Zn-air battery, J. Mater. Chem. A 2019, 7, 15271‒15277.  doi: 10.1039/C9TA03828K

    41. [41]

      Chen, C.; Sun, X.; Yan, X.; Wu, Y.; Liu, H.; Zhu, Q.; Bediako, B. B. A.; Han, B. Boosting CO2 electroreduction on N, P-Co-doped carbon aerogels. Angew. Chem. Int. Ed. 2020, 59, 11123‒11129.  doi: 10.1002/anie.202004226

    42. [42]

      Kuhn, P.; Antonietti, M.; Thomas, A. Porous, covalent triazine-based frameworks prepared by ionothermal synthesis. Angew. Chem. Int. Ed. 2008, 47, 3450‒3453.  doi: 10.1002/anie.200705710

    43. [43]

      Zhao, Y. F.; Yao, K. X.; Teng, B. Y.; Zhang, T.; Han, Y. A perfluorinated covalent triazine-based framework for highly selective and water-tolerant CO2 capture. Energy Environ. Sci. 2013, 6, 3684‒3692.  doi: 10.1039/c3ee42548g

    44. [44]

      Puthiaraj, P.; Lee, Y. R.; Zhang, S. Q.; Ahn, W. S. Triazine-based covalent organic polymers: design, synthesis and applications in heterogeneous catalysis. J. Mater. Chem. A 2016, 4, 16288‒16311.  doi: 10.1039/C6TA06089G

    45. [45]

      Cheng, Z.; Fang, W.; Zhao, T. S.; Fang, S. Q.; Bi, J. H.; Liang, S. J.; Li, L. Y.; Yu, Y.; Wu, L. Efficient visible-light-driven photocatalytic hydrogen evolution on phosphorus-doped covalent triazine-based frameworks. ACS Appl. Mater. Interfaces 2018, 10, 41415‒41421.  doi: 10.1021/acsami.8b16013

    46. [46]

      Hao, L.; Zhang, S. S.; Liu, R. J.; Ning, J.; Zhang, G. J.; Zhi, L. J. Bottom-up construction of triazine-based frameworks as metal-free electrocatalysts for oxygen reduction reaction. Adv. Mater. 2015, 27, 3190‒3195.  doi: 10.1002/adma.201500863

    47. [47]

      Wu, J.; Liu, M.; Sharma, P. P.; Yadav, R. M.; Ma, L.; Yang, Y.; Zou, X.; Zhou, X. D.; Vajtai, R.; Yakobson, B. I.; Lou, J.; Ajayan, P. M. Incorporation of nitrogen defects for efficient reduction of CO2 via two-electron pathway on three-dimensional graphene foam. Nano Lett. 2016, 16, 466‒470.  doi: 10.1021/acs.nanolett.5b04123

    48. [48]

      Xu, J.; Kan, Y.; Huang, R.; Zhang, B.; Wang, B.; Wu, K. H.; Lin, Y.; Sun, X.; Li, Q.; Centi, G.; Su, D. Revealing the origin of activity in nitrogen-doped nanocarbons towards electrocatalytic reduction of carbon dioxide. 2016, 9, 1085‒1089.

    49. [49]

      Wang, R.; Sun, X.; Ould-Chikh, S.; Osadchii, D.; Bai, F.; Kapteijn, F.; Gascon, J. Metal-organic-framework-mediated nitrogen-doped carbon for CO2 electrochemical reduction. ACS Appl. Mater. Interfaces 2018, 10, 14751‒14758.  doi: 10.1021/acsami.8b02226

    50. [50]

      Lu, X.; Tan, T. H.; Ng, Y. H.; Amal, R. Highly selective and stable reduction of CO2 to CO by a graphitic carbon nitride/carbon nanotube composite electrocatalyst. Chem. Eur. J. 2016, 22, 11991‒11996.  doi: 10.1002/chem.201601674

    51. [51]

      Zhu, Q.; Ma, J.; Kang, X.; Sun, X.; Hu, J.; Yang, G.; Han, B. Electrochemical reduction of CO2 to CO using graphene oxide/carbon nanotube electrode in ionic liquid/acetonitrile system. Sci. China Chem. 2016, 59, 551‒556.  doi: 10.1007/s11426-016-5584-1

    52. [52]

      Li, W.; Seredych, M.; Rodriguez-Castellon, E.; Bandosz, T. J. Metal-free nanoporous carbon as a catalyst for electrochemical reduction of CO2 to CO and CH4. ChemSusChem. 2016, 9, 606‒616.  doi: 10.1002/cssc.201501575

    53. [53]

      Ghausi, M. A.; Xie, J.; Li, Q.; Wang, X.; Yang, R.; Wu, M.; Wang, Y.; Dai, L. CO2 overall splitting by a bifunctional metal-free electrocatalyst. Angew. Chem. Int. Ed. 2018, 57, 13135‒13139.  doi: 10.1002/anie.201807571

    54. [54]

      Wang, Y. S.; Chen, J. X.; Wang, G. X.; Li, Y.; Wen, Z. H. Perfluorinated covalent triazine framework derived hybrids for the highly selective electroconversion of carbon dioxide into methane. Angew. Chem. Int. Ed. 2018, 57, 13120‒13124.  doi: 10.1002/anie.201807173

    55. [55]

      Kumar, B.; Asadi, M.; Pisasale, D.; Sinha-Ray, S.; Rosen, B. A.; Haasch, R.; Abiade, J.; Yarin, A. L.; Salehi-Khojin, A. Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction. Nat. Commun. 2013, 4, 2819.  doi: 10.1038/ncomms3819

    56. [56]

      Zhang, C.; Mahmood, N.; Yin, H.; Liu, F.; Hou, Y. Synthesis of phosphorus-doped graphene and its multifunctional applications for oxygen reduction reaction and lithium ion batteries. Adv. Mater. 2013, 25, 4932‒4937.  doi: 10.1002/adma.201301870

    57. [57]

      Yi, J. D.; Xu, R.; Wu, Q.; Zhang, T.; Zang, K. T.; Luo, J.; Liang, Y. L.; Huang, Y. B.; Cao, R. Atomically dispersed iron-nitrogen active sites within porphyrinic triazine-based frameworks for oxygen reduction reaction in both alkaline and acidic media. ACS Energy Lett. 2018, 3, 883‒889.  doi: 10.1021/acsenergylett.8b00245

    58. [58]

      Chen, Y.; Li, J.; Mei, T.; Hu, X. G.; Liu, D.; Wang, J.; Hao, M.; Li, J.; Wang, J.; Wang, X. Low-temperature and one-pot synthesis of sulfurized graphene nanosheets via in situ doping and their superior electrocatalytic activity for oxygen reduction reaction. J. Mater. Chem. A 2014, 2, 20714‒20722.  doi: 10.1039/C4TA04938A

    59. [59]

      Fang, X. X.; Ma, L. B.; Liang, K.; Zhao, S. J.; Jiang, Y. F.; Ling, C.; Zhao, T.; Cheang, T. Y.; Xu, A. W. The doping of phosphorus atoms into graphitic carbon nitride for highly enhanced photocatalytic hydrogen evolution. J. Mater. Chem. A 2019, 7, 11506‒11512.  doi: 10.1039/C9TA01646E

    60. [60]

      Deng, W.; Zhang, L.; Li, L.; Chen, S.; Hu, C.; Zhao, Z. J.; Wang, T.; Gong, J. Crucial role of surface hydroxyls on the activity and stability in electrochemical CO2 reduction. J. Am. Chem. Soc. 2019, 141, 2911‒2915.  doi: 10.1021/jacs.8b13786

    61. [61]

      Firet, N. J.; Smith, W. A. Probing the reaction mechanism of CO2 electroreduction over Ag films via operando infrared spectroscopy. ACS Catal. 2017, 7, 606‒612.  doi: 10.1021/acscatal.6b02382

    62. [62]

      Zhu, S.; Li, T.; Cai, W. B.; Shao, M. CO2 Electrochemical reduction as probed through infrared spectroscopy. ACS Energy Lett. 2019, 4, 682‒689.  doi: 10.1021/acsenergylett.8b02525

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