Citation: Jing SUN, Cao-Ming YU, Li-Zhen CAI, Guo-Cong GUO. Synthesis, Photochromism and Switchable Photoluminescence of a Cd-based Metalloviologen Complex[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1177-1182. doi: 10.14102/j.cnki.0254–5861.2011–3101 shu

Synthesis, Photochromism and Switchable Photoluminescence of a Cd-based Metalloviologen Complex

Jing SUN ^a ,
Cao-Ming YU ^{a, b} ,
Li-Zhen CAI ^a,, ,
Guo-Cong GUO ^a,,

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Chemical Engineering, Fuzhou University, Fuzhou 350116, China

Corresponding author: Li-Zhen CAI, clz@fjirsm.ac.cn Guo-Cong GUO, gcguo@fjirsm.ac.cn
Received Date: 18 January 2021
Accepted Date: 9 March 2021

Fund Project: the program of the Chinese Academy of Sciences XDB20010100the program of the Chinese Academy of Sciences QYZDB-SSW-SLH020the NSF of China 21827813the NSF of China 21871264the NSF of Fujian Province 2018J05036the NSF of Fujian Province 2018J01028

Figures(3)

A novel metalloviologen complex {[Cd(PhSQ)(HTBC)(H₂O)₂]·1.25H₂O}_n (1) based on N-(4-sulfo-phenyl)-4, 4΄-bipyridinium (PhSQ) and monoprotonated trimesic acid (HTBC) has been prepared and structurally characterized. Complex 1 has been characterized by elemental analysis, IR, thermogravimetric analyses, UV-Vis spectra and X-ray crystallography. The coordination geometry of Cd(II) ion is a pentagonal bipyramid. Complex 1 displays a zigzag chain along the b axis, and such chains are extended into a 2D layer supramolecular network through hydrogen bonding and π…π interactions. Moreover, complex 1 exhibits reversible photochromic and switchable luminescent behaviors via UV light irradiation at room temperature induced by the photogenerated radicals via a photo-induced electron transfer (PET) mechanism.
- crystal structure,
- metalloviologen,
- photochromism,
- switchable photoluminescence
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