Citation: Yun-Zhu LIU, Xiao-Na LI, Sheng-Gui HE. Activation of Carbon Dioxide by Gas-phase Metal Species[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1385-1403. doi: 10.14102/j.cnki.0254–5861.2011–3081 shu

Activation of Carbon Dioxide by Gas-phase Metal Species

Yun-Zhu LIU ^{a, b, c} ,
Xiao-Na LI ^{a, c,,} ,
Sheng-Gui HE ^{a, b, c}

a.
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China

Corresponding author: Xiao-Na LI, lxn@iccas.ac.cn
Received Date: 28 December 2020
Accepted Date: 23 February 2021

Fund Project: the National Natural Science Foundation of China 22022308the National Natural Science Foundation of China 21773254the K. C. Wong Education Foundation, and the Youth Innovation Promotion Association CAS 2016030

Figures(9)

Catalytic conversion of carbon dioxide (CO₂) into value-added chemicals is an important and active field in both of the condensed-phase and gas-phase studies. This mini-review summarizes a variety of experimentally identified reactions in the activation and transformation of CO₂ by metal species in the gas phase. The use of advanced mass spectrometric instrumentation in conjunction with quantum chemistry calculations can uncover the mechanistic details and determine the vital factors that control the activation of CO₂. This review focuses mainly on three topics: the activation of CO₂ by (1) bare metal ions and metal oxide species, (2) metal hydrides, and (3) other gas-phase metal species. Emphasis is placed on the latest advances in the hydrogenation of CO₂ mediated with metal hydrides. A potential prospect toward the future effort in the activation and transformation of CO₂ in gas phase has also been discussed.
- carbon dioxide activation,
- gas-phase metal species,
- mass spectrometry,
- quantum chemistry calculations
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