Citation: Chang-Hong LI, Yu-Lin LI, Wei LI, Yun-Fei KUANG. Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Nickel(III) Complex with 3-(Pyridin-2-yl)-1, 2, 4-triazole[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 363-368. doi: 10.14102/j.cnki.0254–5861.2011–2931 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Nickel(III) Complex with 3-(Pyridin-2-yl)-1, 2, 4-triazole

a.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China
b.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: Chang-Hong LI, lichanghong4444@126.com; li_weihnxy@163.com
Received Date: 30 June 2020
Accepted Date: 14 August 2020

Fund Project: the Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093Industry and Research Key Project of Hengyang City 2018kKJ016

Figures(6)

A new binuclear nickel(II) complex Ni₂(HPT)₄(H₂O)₃ (1) has been hydrothermally synthesized with nickel hydroxide, 3, 4-pyridine dicarboxylic acid and 3-(pyridin-2-yl)-1, 2, 4-triazole (HPT) in the mixed solution (the volume ratio of methanol and water is 1:4). It crystallizes in tetragonal space group P4₂/n, with a = 20.844(1), b = 20.844(1), c = 7.2463(7) Å, V = 3148.2(5) Å³, D_c = 1.587 g/cm³, Z = 4, μ(MoKa) = 1.257, F(000) = 1544, the final GOOF = 1.043, R = 0.0437 and wR = 0.1297. The crystal structure shows that the whole molecule consists of two nickel ions which are bridged by four μ₂-η¹: η⁰-3-(pyridin-2-yl)-1, 2, 4-triazole anions. The coordination environment of Ni(II) ion is NiN₆, giving a distorted octahedral geometry. The thermal stability and fluorescent and magnetic properties of the complex were investigated.
- binuclear nickel(II) complex,
- thermal stability,
- fluorescent and magnetic properties
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