Citation: Zong-Jie GUAN, Quan-Ming WANG. Ligand Engineering in Metal Nanoclusters: from Structural Control to Functional Modulation[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1194-1200. doi: 10.14102/j.cnki.0254–5861.2011–2928 shu

Ligand Engineering in Metal Nanoclusters: from Structural Control to Functional Modulation

Zong-Jie GUAN ,
Quan-Ming WANG ^,

Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Tsinghua University, Beijing 100084, China

Corresponding author: Quan-Ming WANG, qmwang@tsinghua.edu.cn
Received Date: 28 June 2020
Accepted Date: 5 July 2020

Fund Project: the National Natural Science Foundation of China 91961201the National Natural Science Foundation of China 21631007the National Natural Science Foundation of China 21971136

Figures(6)

Ligand-protected metal nanoclusters have drawn increasing research interest because of their unique physicochemical properties and practical applications. Great efforts have been made in pursuing rational synthesis of metal nanoclusters and establishing the structure-property relationships. As an indispensable part of ligand-protected metal nanoclusters, ligands play multiple roles in determining their structures and properties. In this perspective, we demonstrate the importance of ligand engineering in terms of the control of structures, optical and catalytic properties of metal nanoclusters. Furthermore, we will show that ligand engineering is prospective in structural design and preorganization of surface metal sites.
- metal nanoclusters,
- physicochemical properties,
- structure-property relationship,
- ligand engineering
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