Citation: Xue-Ting WANG, Wei WEI, Kai ZHANG, Shao-Wu DU. Detection of Diethyl Ether by a Europium MOF through Fluorescence Enhancement[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 369-375. doi: 10.14102/j.cnki.0254–5861.2011–2917 shu

Detection of Diethyl Ether by a Europium MOF through Fluorescence Enhancement

Xue-Ting WANG ^{a, b} ,
Wei WEI ^b ,
Kai ZHANG ^b ,
Shao-Wu DU ^{a, b,,}

a.
Fujian Key Laboratory of Functional Marine Sensing Materials, Minjiang University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Shao-Wu DU, swdu@fjirsm.ac.cn
Received Date: 23 June 2020
Accepted Date: 1 September 2020

Fund Project: the National Natural Science Foundation of China 21972060

Figures(8)

A new water-stable europium MOF, (Me₂NH₂)[Eu(abtc)(phen)]·2H₂O (1), has been synthesized from Eu(NO₃)₃·6H₂O with 1, 10-phenanthroline (phen) and 3, 3′, 5, 5′-azobenzenetetracarboxylic acid (H₄abtc) ligands under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis, IR, TGA and PXRD. It crystallizes in monoclinic system, C2/c space group, with a = 16.278(3), b = 14.261(3), c = 27.936(5) Å, β = 103.464(3)°, V = 6307(2) Å³, Z = 8, C₃₀H₂₆EuN₅O₁₀, M_r = 768.5, D_c = 1.543 g/cm³, F(000) = 2912, μ(MoKa) = 2.044 mm^‒1, R = 0.0315 and wR = 0.0663. In the structure of 1, the EuO₇N₂ polyhedra are assembled into a 2D layer with rhombic windows and these layers are further condensed to form a 3D framework. It can be used as selective and sensitive fluorescence sensors capable of detecting diethyl ether vapor.
- lanthanide MOF,
- water stable,
- fluorescence enhancement,
- diethyl ether detection
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