Citation: Rui WANG, Wen-Tao XU, Zi-Xuan QIN, Jun-Rong LING, You-Fu ZHOU. Synthesis of High-purity Fe₂AlB₂ and the Effect as Sintering Additive for ZrB₂[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 283-290. doi: 10.14102/j.cnki.0254–5861.2011–2882 shu

Synthesis of High-purity Fe₂AlB₂ and the Effect as Sintering Additive for ZrB₂

Rui WANG ^{a, b} ,
Wen-Tao XU ^b ,
Zi-Xuan QIN ^{b, c} ,
Jun-Rong LING ^{b, c} ,
You-Fu ZHOU ^b,,

a.
Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China
b.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: You-Fu ZHOU, yfzhou@fjirsm.ac.cn
Received Date: 19 May 2020
Accepted Date: 10 October 2020

Fund Project: the grants of CAS Priority Research Program XDB20010300the grants of CAS Priority Research Program XDA21010204Science and Technology Program of Fujian Province 2017T3001

Figures(11)

Fe₂AlB₂ powder material was prepared by the direct reaction of iron, aluminum and boron powders in a tubular furnace. The effects of different Al contents, temperature and raw material pretreatment on the purity of product were studied. The mixed powder with the stoichiometric ratio of 1.5Al/2Fe/2B was processed by CIP (Cold Isostatic Pressing), and then calcined at 1150 ℃ for 120 min. The product containing a small amount of impurities is treated with alkaline solution to obtain high-purity Fe₂AlB₂ powder. ZrB₂-Fe₂AlB₂ composite ceramic was successfully prepared at 1250 ℃ by hot pressing sintering. The density, hardness and fracture toughness were 96.2%, 22 ± 0.3 GPa and 5.78 ± 0.5 MPa·m^1/2, respectively.
- MAB phase,
- ternary layered structure,
- high purity,
- ZrB₂
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Synthesis of High-purity Fe₂AlB₂ and the Effect as Sintering Additive for ZrB₂