Citation: Jun-Yi LI, Xiang CHEN, Liang TONG, Si-Yu DENG, Li-Zhuang CHEN. Two Low-temperature Phase Transition Compounds Based on Quinuclidine Derivatives with Fluorescence[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 149-159. doi: 10.14102/j.cnki.0254–5861.2011–2874 shu

Two Low-temperature Phase Transition Compounds Based on Quinuclidine Derivatives with Fluorescence

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Si-Yu DENG, dsy543210@163.com Li-Zhuang CHEN, clz1977@sina.com
Received Date: 11 May 2020
Accepted Date: 8 July 2020

Fund Project: the National Natural Science Foundation of China 21671084the Six talent peaks project in Jiangsu Province 2014-XCL-008the Qing Lan Project of Jiangsu Province and the Foundation of Jiangsu Educational Committee 16KJB430011

Figures(12)

Two phase transition materials [iPrQ]₂MnBr₄ (1, iPrQ = N-isopropyl-quinuclidinium) and [iPrQ]₂MnCl₄ (2) were synthesized and characterized. Dielectric measurements and differential scanning calorimetry showed that the two compounds underwent reversible phase transitions at ca. –47 and –37 ℃, respectively. Variable-temperature single-crystal X-ray diffraction suggested that the two compounds underwent the same phase transitions from space group C2/c to Cc but at different temperature. The variable crystal structures indicated that the structural phase transitions of the compound were ascribed to the torsional movement of quinuclidine ring and the disappearance of the c-slide plane. The second harmonic generation (SHG) response further proved this structural phase transition. Fluorescence tests showed that the two compounds have strong fluorescence. The strong variations in dielectric anomalies make compounds 1 and 2 suitable for promising switchable dielectric materials.
- quinuclidine derivatives,
- fluorescent compounds,
- crystal structure,
- second harmonic generation (SHG),
- permittivity properties
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