Citation: Xiu-Ying LI, Lin GAO, Guang-Bo CHE, Yong-Sheng YAN, Chun-Xiang LI. A Fe(II) Coordination Polymer Based on 1, 10-Phenanthroline Derivative and Oxalic Acid: Synthesis, Structure, and Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 317-323. doi: 10.14102/j.cnki.0254–5861.2011–2857 shu

A Fe(II) Coordination Polymer Based on 1, 10-Phenanthroline Derivative and Oxalic Acid: Synthesis, Structure, and Properties

Xiu-Ying LI ^{a, b} ,
Lin GAO ^c ,
Guang-Bo CHE ^b,, ,
Yong-Sheng YAN ^a ,
Chun-Xiang LI ^a,,

a.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
b.
College of Chemistry, Jilin Normal University, Siping 136000, China
c.
College of Environmental Engineering, Jilin Normal University, Siping 136000, China

Corresponding author: Guang-Bo CHE, guangboche@jlnu.edu.cn Chun-Xiang LI, lcx@ujs.edu.cn
Received Date: 21 April 2020
Accepted Date: 28 June 2020

Fund Project: the National Natural Science Foundation of China 21576112the Project of Department of Science & Technology of Jilin Province 20180623042TCNatural Science Foundation Project of Jilin Province 20170520143JHthe China Postdoctoral Science Foundation 2017M611732the Science and Technology Research Projects of the Education Department of Jilin Province No. JJKH20180791KJthe Science and Technology Development Plan of Siping City 2017056

Figures(10)

A Fe-based coordination polymer, [Fe(C₂O₄)_0.5(4-NCP)]_n·2nH₂O (1, 4-HNCP = 2-(4-carboxy- phenyl)-1H-imidazo(4, 5-f)-(1, 10)phenanthroline, H₂C₂O₄ = oxalic acid), was hydrothermally synthesized and characterized by infrared spectrum, elemental analysis, single-crystal X-ray diffraction, power X-ray diffraction, and UV-vis absorption spectrum. Structural analyses reveal that polymer 1 possesses a (4, 4)-connected 2D network. In addition, 1 shows photocatalytic activity toward the degradation of rhodamine B (RhB) in the presence of H₂O₂ under visible light illumination.
- Fe-based coordination polymer,
- hydrothermal synthesis,
- crystal structure,
- photocatalytic activity
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