Citation: Tian-Pu SHENG, Feng-Rong DAI, Guo-Zong ZHENG, Zhong-Ning CHEN. Synthesis, Crystal Structure and Gas Adsorption Properties of Metal-organic Supercontainer Based 2, 6-Naphthalenedicarboxylate Linker[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 311-316. doi: 10.14102/j.cnki.0254–5861.2011–2855 shu

Synthesis, Crystal Structure and Gas Adsorption Properties of Metal-organic Supercontainer Based 2, 6-Naphthalenedicarboxylate Linker

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Guo-Zong ZHENG, Zhengguozong@fjirsm.ac.cn
Received Date: 17 April 2020
Accepted Date: 2 June 2020

Fund Project: the National Natural Science Foundation of China 21673239the National Natural Science Foundation of China 21501179

Figures(6)

A new sulfonylcalixarene-based coordination container 1 was designed and synthesized from the self-assembly reaction of p-tert-butylsulfonylcalix[4]arene (TBSC), Co(II) ion, and 2, 6-naphthalenedicarboxylic acid (NDC). It crystallizes in tetragonal system, space group I4/m with a = b = 30.9119(19) Å, c = 43.565(3) Å, V = 41628(6) Å³, D_c = 0.731 g/cm³, M_r = 9162.36, C₃₈₄H₃₄₈Co₂₄O₁₂₆S₂₄, Z = 2, F(000) = 9384, μ = 0.566 mm^–1, the final GOOF = 1.027, R = 0.0987 and wR = 0.2474 for 7240 observed reflections with I > 2σ(I). Structural analyses indicate that 1 adopts an edge-directed octahedral geometry and consists of six TBSC-supported Co₄ tetranuclear units locating on the vertices and twelve NDC bridging ligands occupying the edges. The new compound exhibits outstanding performance for the C₂ hydrocarbons separation over CH₄.
- coordination container,
- sulfonylcalix[4]arene,
- gas separation,
- self-assembly
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