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Citation: Ai-Ping ZHENG, Mei-Yan GAO, Wei-Hui FANG, Yao KANG. Two Novel {Ti6P2} Clusters Decorated with Inorganic Acids[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 277-282. doi: 10.14102/j.cnki.0254–5861.2011–2853 shu

Two Novel {Ti6P2} Clusters Decorated with Inorganic Acids

  • a.

    College of Chemistry, Fuzhou University, Fuzhou 350100, China

  • b.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Wei-Hui FANG, fwh@fjirsm.ac.cn Yao KANG, ky@fjirsm.ac.cn
  • Received Date: 17 April 2020
    Accepted Date: 15 June 2020

    Fund Project: National Natural Science Foundation of China 21771181National Natural Science Foundation of China 21935010National Natural Science Foundation of China 21973096Youth Innovation Promotion Association CAS 2017345

Figures(5)

  • Two inorganic acids decorating titanium-oxo clusters (PTCs), Ti6O4(OiPr)10(O3P-Phen)2(NO3)2 (PTC-251) and Ti6O4(OiPr)10(O3P-Phen)2(HSO4)2 (PTC-252) (H2O3P-Phen = phenylphosphinic acid) have been synthesized under solvothermal conditions. As a result of the labile coordination sites of the {Ti6P2} unit, nitrite and sulfate adopt different capping mode. Besides, they also present different space packing. The photocatalytic H2 evolution activities of these obtained PTCs have been studied, with sulfate decorating PTC-252 presenting a maximum H2 production rate up to 110.95 μmol·g-1·h-1.
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