Citation: Zai-Chun HUANG, Xiao-Fang WANG, Bi Foua Claude Alain GOHI, Yu-Feng LI, Yao KANG, Zhi-Qiang JIANG. Urothermal Syntheses of Chiral Zincic Benzotriazole-5-carboxylate Frameworks for Iodine Uptake[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 199-206. doi: 10.14102/j.cnki.0254–5861.2011–2796 shu

Urothermal Syntheses of Chiral Zincic Benzotriazole-5-carboxylate Frameworks for Iodine Uptake

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Deep-processing of Fine Flake Graphite Sichuan Province Key Laboratory of Colleges and Universities, Panzhihua University, Panzhihua 617000, China
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State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Bi Foua Claude Alain GOHI, claudefouabi@hotmail.fr Yao KANG, ky@fjirsm.ac.cn Zhi-Qiang JIANG, myjiangzq@163.com
Received Date: 5 March 2020
Accepted Date: 12 May 2020

Fund Project: the Science and Technology Planning Project in Sichuan Province 2019YJ0686the Science and Technology Planning Project in Panzhihua City 2019ZD-G-11

Figures(5)

So far, the synthesis of chiral framework with achiral organic ligand still faces great challenge. Herein, three new coordinated complexes [Zn(btca)Cl]·DMA·N(CH₃)₂ (1), [Zn(btca)(Ac^-)]·N(CH₃)₂ (2) and [Zn(btca)]·H₂O (3) (DMA = N, N-dimethylacetamide, btca = benzotriazole-5-carboxylate acid) were synthesized via different methods. Single-crystal X-ray diffraction analysis revealed that compounds 1 and 2 were isostructural and showed achiral layer network with fes topology, and 3 presented a chiral three-dimensional framework with eta topology. The result of this work has demonstrated that urothermal synthesis will be promising means of constructing chiral framework with achiral building block. Compound 3 also displayed an excellent property of iodine uptake.
- urothermal synthesis,
- benzotriazole-5-carboxylate acid,
- chirality,
- I₂ absorption
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